THE VAPOR PRESSURE OF VINYL ACETATE

1933 ◽  
Vol 9 (5) ◽  
pp. 419-423 ◽  
Author(s):  
J. Marsden ◽  
A. C. Cuthbertson
Keyword(s):  
Critical Temperature ◽  
Vapor Pressure ◽  
Vinyl Acetate ◽  
Boiling Point ◽  
Normal Boiling Point ◽  
Temperature Range ◽  
Heat Of Evaporation

This paper presents the results of the measurement of the vapor pressure of vinyl acetate, over the temperature range from 0 °C. to the normal boiling point. The determinations were carried out on vacuum distilled samples with an isoteniscope, differing slightly in detail from that used by Smith and Menzies(7).The normal boiling point is 72.5 °C. The molecular heat of evaporation has been found to be 8211 calories. The equation which represents the results is[Formula: see text]Trouton's constant and the critical temperature have been found to be 23.8 and 228.3 °C.

On the Critical Temperature, Normal Boiling Point, and Vapor Pressure of Ionic Liquids

2005 ◽  
Vol 109 (13) ◽  
pp. 6040-6043 ◽  
Author(s):  
Luis P. N. Rebelo ◽  
José N. Canongia Lopes ◽  
José M. S. S. Esperança ◽  
Eduardo Filipe
Keyword(s):  
Ionic Liquids ◽  
Critical Temperature ◽  
Vapor Pressure ◽  
Boiling Point ◽  
Normal Boiling Point

Exciplex-Based Vapor/Liquid Visualization Systems Appropriate for Automotive Gasolines

1993 ◽  
Vol 47 (6) ◽  
pp. 782-786 ◽  
Author(s):  
Lynn A. Melton
Keyword(s):  
Cross Talk ◽  
Spectral Region ◽  
Boiling Point ◽  
Automotive Gasoline ◽  
Normal Boiling Point ◽  
Tertiary Amines ◽  
Temperature Range ◽  
Exciplex Emission ◽  
Visualization Systems ◽  
Vapor Liquid

This paper reports the development of exciplex-based vapor/liquid visualization systems based on exciplexes formed from tertiary amines and fluorine-substituted benzene and/or toluene. These systems are expected to be virtually coevaporative with solvents (fuels) boiling in the temperature range 70 to 110°C and thus are expected to track the vaporization of automotive gasoline effectively. A system consisting of 10% triethylamine/0.5% fluorobenzene/89.5% hexane should be coevaporative with a normal boiling point of 69°C. A system consisting of 10% n-propyldiethylamine/0.5% 4-fluorotoluene/89.5% isooctane should be coevaporative with a normal boiling point of approximately 100°C. Although the coevaporation of these systems is excellent, the exciplexes revert to varying extents to excited monomer at temperatures near 100°C. Thus there is considerable cross talk from the liquid into the vapor spectral region. The tertiary amines generally require excitation at wavelengths below 250 nm; the fluorobenzene or 4-fluorotoluene can be excited at 266 nm. Monomer emission peaks at 290 nm; exciplex emission peaks at 350 nm.

Electrical Conductivity of Molten ZnCl2 at Temperature as High as 1421 K

2015 ◽  
Vol 70 (2) ◽  
pp. 133-134
Author(s):  
Alexander B. Salyulev ◽  
Alexei M. Potapov
Keyword(s):  
Electrical Conductivity ◽  
Vapor Pressure ◽  
Wide Temperature Range ◽  
Boiling Point ◽  
Temperature Range

AbstractThe electrical conductivity of molten ZnCl2 was measured in a wide temperature range (ΔT=863 K) to a temperature as high as 1421 K that is 417 degrees above the boiling point of the salt. At the temperature maximum of the own vapor pressure of the salt reached several megapascals.

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