The high-resolution infrared spectrum of BrCl

1994 ◽  
Vol 72 (11-12) ◽  
pp. 1145-1154 ◽  
Author(s):  
Hiromichi Uehara ◽  
Toichi Konno ◽  
Yasushi Ozaki ◽  
Koui Horiai ◽  
Kuniaki Nakagawa ◽  
...  
Keyword(s):  
Fourier Transform ◽  
Standard Deviation ◽  
High Resolution ◽  
Infrared Spectrum ◽  
Potential Function ◽  
Internuclear Distance ◽  
Spectral Lines ◽  
Fourier Transform Spectrometer ◽  
Isotopic Species ◽  
Correction Terms

The high-resolution infrared spectrum of BrCl has been observed with a Fourier transform spectrometer. About 850 spectral lines for the Δν = 1 sequences of the four isotopic species, 79Br35Cl, 81Br35Cl, 79Br37Cl, and 81Br37Cl have been measured between 417 and 461 cm−1. They have been fitted with a standard deviation of 0.000 146 cm−1 to a Dunham potential function using eight coefficients that included two Watson-type Δ correction terms. Dunham Yij coefficients have been derived for each of the four isotopic species. The equilibrium internuclear distance re of BrCl is 2.136 053 28 (67) Å.

High-Resolution Infrared Spectrum of Diazirine, H2CN2. Rovibrational Analysis of the Methylene Deformation Band

1988 ◽  
Vol 43 (4) ◽  
pp. 331-337 ◽  
Author(s):  
A. Gambi ◽  
A. Baldacci ◽  
S. Giorgianni
Keyword(s):  
Fourier Transform ◽  
High Resolution ◽  
Infrared Spectrum ◽  
Least Squares ◽  
Deformation Band ◽  
Fourier Transform Spectrometer ◽  
Centrifugal Distortion ◽  
Molecular Constants ◽  
Centrifugal Distortion Constants

Abstract The infrared spectrum of diazirine has been recorded at Doppler resolution with a high informa­tion Fourier transform spectrometer. The ν3 fundamental has been reinvestigated and the overall assignment of the rovibrational transitions has been carried out. From the least-squares analysis a more accurate set of molecular constants including the sextic centrifugal distortion constants has been determined for the level υ3 = 1 and will be reported here. The higher resolution achieved here allowed the assignment of weaker lines and many Q branch transitions. Moreover many blended lines have now been resolved and could be properly assigned.

Infrared spectrum and molecular constants of CO2 in the 1.4–1.7 μm atmospheric window by very high resolution Fourier transform spectroscopy

1980 ◽  
Vol 58 (11) ◽  
pp. 1560-1569 ◽  
Author(s):  
J. P. Maillard ◽  
M. Cuisenier ◽  
Ph. Arcas ◽  
E. Arié ◽  
C. Amiot
Keyword(s):  
Fourier Transform ◽  
High Resolution ◽  
Infrared Spectrum ◽  
Accurate Determination ◽  
Spectroscopic Constants ◽  
Fourier Transform Spectrometer ◽  
Molecular Constants ◽  
Atmospheric Window ◽  
Very High

The spectrum of CO2 has been recorded in the 1.4–1.7 μm atmospheric window using the very high resolution Fourier transform spectrometer of the Meudon Observatory. This laboratory study has allowed the accurate determination of the spectroscopic constants previously evaluated from the Venus spectrum.

scholarly journals Analysis of new species retrieved from MIPAS

2014 ◽  
Vol 56 ◽  
Author(s):  
Shaomin Cai ◽  
Anu Dudhia
Keyword(s):  
Fourier Transform ◽  
New Species ◽  
High Resolution ◽  
Trace Gases ◽  
Michelson Interferometer ◽  
Emission Spectra ◽  
Fourier Transform Spectrometer ◽  
Mid Infrared ◽  
The Third ◽  
Atmospheric Sounding

The Michelson Interferometer for Passive Atmospheric Sounding (MIPAS) instrument which operated on the Envisat satellite from 2002-2012 is a Fourier transform spectrometer for the measurement of high-resolution gaseous emission spectra at the Earth's limb. It operates in the near- to mid-infrared, where many of the main atmospheric trace gases have important emission features. The initial operational products were profiles of Temperature, H2O, O3, CH4, N2O, HNO3, and NO2, and this list was recently extended to include N2O5, ClONO2, CFC-11 and CFC-12. Here we present preliminary results of retrievals of the third set of species under consideration for inclusion in the operational processor: HCN, CF4, HCFC-22, COF2 and CCl4.

The spectrum of gaseous methane at 77 K in the 1.1 – 2.6 μm region: a benchmark for planetary astronomy

1989 ◽  
Vol 67 (11) ◽  
pp. 1027-1035 ◽  
Author(s):  
A. R. W. McKellar
Keyword(s):  
Fourier Transform ◽  
High Resolution ◽  
Low Temperature ◽  
Spectral Resolution ◽  
Fourier Transform Spectrometer ◽  
Absorption Cell ◽  
Model Calculations ◽  
Testing Model ◽  
Medium Resolution ◽  
Spectrometer Data

The spectrum of CH4 obtained in CH4 plus N2 mixtures at a temperature of 77 K has been recorded with a spectral resolution of 0.14 cm−1 in the region 3800 to 9100 cm−1. The experiments were performed with long paths (66 or 88 m) in a cooled absorption cell using a Fourier-transform spectrometer. Data are presented here at low and medium resolution, and examples of some spectral regions are also shown at high resolution. The complete results are available from the author in an Appendix. Comparisons are made with previous model calculations of CH4 absorption, and with the observed spectrum of Neptune's satellite, Triton. The results should be useful for the interpretation of the spectra of Triton, Titan, and Pluto. They will also be of value for testing model calculations of low-temperature CH4 absorption, which, thus verified, can be used with greater confidence to analyze observations of Jupiter, Saturn Uranus, and Neptune.

scholarly journals High-Resolution Infrared Spectroscopy of the v1+ v4Band of14NF3:Reductions of the Rovibrational Hamiltonian

2012 ◽  
Vol 9 (1) ◽  
pp. 253-259 ◽  
Author(s):  
Hamid Najib ◽  
Siham Hmimou ◽  
Hicham Msahal
Keyword(s):  
Experimental Data ◽  
Fourier Transform ◽  
Infrared Spectroscopy ◽  
Excited State ◽  
High Resolution ◽  
Infrared Spectrum ◽  
Fourier Transform Infrared ◽  
Sixth Order ◽  
Degenerate State ◽  
Unitary Equivalence

The high-resolution Fourier transform infrared spectrum of nitrogen trifluoride NF3has been studied in the v1+ v4perpendicular band region around 1523 cm−1. All experimental data have been refined applying various reduction forms of the effective rovibrational Hamiltonian developed for an isolated degenerate state of a symmetric top molecule. The v1= v4= 1 excited state of the14NF3oblate molecule was treated with models taking into account ℓ- andk-type intravibrational resonances. Parameters up to sixth order have been accurately determined and the unitary equivalence of the derived parameter sets in different reductions was demonstrated.

Far-infrared high-resolution Fourier transform spectrometer

1987 ◽  
Vol 26 (18) ◽  
pp. 3818 ◽  
Author(s):  
Bruno Carli ◽  
Massimo Carlotti ◽  
Francesco Mencaraglia ◽  
Enzo Rossi
Keyword(s):  
Fourier Transform ◽  
High Resolution ◽  
Far Infrared ◽  
Fourier Transform Spectrometer
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