Photoreactions of Nitroso Compounds in Solution. XIX Stereochemistry of Nitrosamine Photoaddition to Olefin
Keyword(s):
The stereochemical course of the photoaddition of nitrosamines to a carbon–carbon double bond was shown to follow a free radical mechanism initiated by aminium radicals. The photoaddition to cyclohexene was highly stereoselective in which the addendum approached in anti-diaxial mode. Similar photoadditions to cis- and trans-2-butenes were less stereoselective, giving mixtures of the erythro- and threo-adducts, owing to the rotation of the carbon-carbon single bond in the intermediate stage.
1953 ◽
Vol 31
(12)
◽
pp. 1211-1222
◽
Keyword(s):
2000 ◽
Vol 127
(1)
◽
pp. 61-72
◽
1992 ◽
Vol 17
(sup1)
◽
pp. 161-230
2018 ◽
1985 ◽
Vol 286
(3)
◽
pp. c47-c50
◽
Keyword(s):
1994 ◽
pp. 471-484
◽
Keyword(s):
1972 ◽
Vol 3
(11)
◽
pp. 319-326
◽