The nuclear magnetic resonance spectra and spin-lattice relaxation times have been measured for the protons in
n
-pentane (C
5
H
12
),
n
-hexane (C
6
H
14
) and
cyclo
pentane (C
5
H
10
) all in the solid state. The temperature range covered was from 70° K to the melting-points of 143·4° K for
n
-pentane, 177·8° K for
n
-hexane and 179·4° K for
cyclo
pentane. In the case of
n
-pentane and
n
-hexane the second moments of the absorption lines were found to be smaller than the computed rigid lattice values over the. whole temperature range. Possible molecular motions which might cause this reduction are discussed. It is suggested that the most probable type of motion is reorientation of the methyl groups at the ends of each molecule about the adjacent C—C bonds. An analysis of the spin-lattice relaxation times shows that this reorientation process is governed by an activation energy of 2·7 kcal/mole for
n
-pentane and 2·9 kcal/mole for
n
-hexane, values which support the mechanism postulated. At the lowest temperature the absorption lines had not reached their full widths, even though the reorientation frequencies at these temperatures were considerably less than the line-widths. The experimental second moment for
cyclo
pentane below about 120° K indicates that the lattice is effectively rigid in this temperature region. The uncertainties in both the experimental and theoretical second moments do not allow a distinction to be drawn between the plane and puckered molecular models. At the temperature of the first transition (122·4° K) the line-width second moment and relaxation time all show a sudden decrease. The low value of second moment at the higher temperatures indicates that considerable molecular motion is occurring, the molecules rotating with spherical symmetry. The change in crystal structure at the temperature of the second transition (138·1° K) is thought to be a direct result of this spherical symmetry. As the temperature increases, the results indicate that more molecular motion must be occurring, and it is thought that the rotating molecules are diffusing through the lattice.
15N and 133Cs Solid NMR Studies on Ionic Dynamics in Plastic CsNO2
