scholarly journals TIME IN QUANTUM GEOMETRODYNAMICS

2000 ◽  
Vol 15 (26) ◽  
pp. 4125-4140
Author(s):  
ARKADY KHEYFETS ◽  
WARNER A. MILLER
Keyword(s):  
Standard Approach ◽  
General Covariance ◽  
Quantization Procedure ◽  
Total Problem ◽  
Quantum Geometrodynamics ◽  
Dynamic Variables

We revisit the issue of time in quantum geometrodynamics and suggest a quantization procedure on the space of true dynamic variables. This procedure separates the issue of quantization from enforcing the constraints caused by the general covariance symmetries. The resulting theory, unlike the standard approach, takes into account the states that are off shell with respect to the constraints, and thus avoids the problems of time. In this approach, quantum geometrodynamics, general covariance, and the interpretation of time emerge together as parts of the solution of the total problem of geometrodynamic evolution.

Controlling Gas Selectivity in Molecular Porous Liquids by Tuning the Cage Window Size

2019 ◽  
Author(s):  
Benjamin Egleston ◽  
Konstantin V. Luzyanin ◽  
Michael C. Brand ◽  
Rob Clowes ◽  
Michael E. Briggs ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Chemical Synthesis ◽  
Field Gradient ◽  
Window Size ◽  
Standard Approach ◽  
Porous Solids ◽  
Pulsed Field Gradient Nmr ◽  
Pulsed Field ◽  
Cage Molecules ◽  
Gas Selectivity

Control of pore window size is the standard approach for tuning gas selectivity in porous solids. Here, we present the first example where this is translated into a molecular porous liquid formed from organic cage molecules. Reduction of the cage window size by chemical synthesis switches the selectivity from Xe-selective to CH<sub>4</sub>-selective, which is understood using <sup>129</sup>Xe, <sup>1</sup>H, and pulsed-field gradient NMR spectroscopy.

Controlling Gas Selectivity in Molecular Porous Liquids by Tuning the Cage Window Size

2019 ◽  
Author(s):  
Benjamin Egleston ◽  
Konstantin V. Luzyanin ◽  
Michael C. Brand ◽  
Rob Clowes ◽  
Michael E. Briggs ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Chemical Synthesis ◽  
Field Gradient ◽  
Window Size ◽  
Standard Approach ◽  
Porous Solids ◽  
Pulsed Field Gradient Nmr ◽  
Pulsed Field ◽  
Cage Molecules ◽  
Gas Selectivity

Control of pore window size is the standard approach for tuning gas selectivity in porous solids. Here, we present the first example where this is translated into a molecular porous liquid formed from organic cage molecules. Reduction of the cage window size by chemical synthesis switches the selectivity from Xe-selective to CH<sub>4</sub>-selective, which is understood using <sup>129</sup>Xe, <sup>1</sup>H, and pulsed-field gradient NMR spectroscopy.

The Mismeasurement of Cattle Ownership In Namibia's Northern Communal Areas

2020 ◽  
Vol 24 (2) ◽  
pp. 255-271
Author(s):  
Dylan Groves ◽  
Venomukona Tjiseua
Keyword(s):  
Large Scale ◽  
Rangeland Management ◽  
Standard Approach ◽  
Growing Up ◽  
Ecological Variability ◽  
Pastoralist Communities ◽  
Pastoralist Community ◽  
Livestock Ownership ◽  
Communal Areas ◽  
Collection Methods

The standard approach to measuring livestock ownership in pastoralist communities relies on an assumption of uniformity that does not reflect the diverse concepts of ownership held by pastoralists themselves. In Namibia's Koakaveld Region, Himba and Herero pastoralist communities have a rich vocabulary for categorising the origins, usage rights and cultural valence of their cattle. Drawing on both authors' experience overseeing a large-scale rangeland management programme evaluation in Namibia's Northern Communal Areas – and one author's experience growing up in and keeping cattle in a Himba pastoralist community – we show how the standard approach to measuring cattle ownership undermines accurate estimates of livestock wealth, off-take and inequality, and obfuscates pastoralist's strategies for turning ecological variability to their advantage. We conclude with lessons about how multi-dimensional data collection methods improve upon the standard approach to livestock ownership measurements.

Fmoc Solid Phase Peptide Synthesis

1999 ◽  
Keyword(s):  
Peptide Synthesis ◽  
Solid Phase ◽  
Solid Phase Peptide Synthesis ◽  
Peptide Chain ◽  
Standard Approach ◽  
Side Chain ◽  
Complex Structures ◽  
Protein Conjugation ◽  
Chemoselective Ligation ◽  
Routine Production

In the years since the publication of Atherton and Sheppard's volume, the technique of Fmoc solid-phase peptide synthesis has matured considerably and is now the standard approach for the routine production of peptides. The basic problems outstanding at the time of publication of this earlier work have now been, for the most part, solved. As a result, innovators in the field have focussed their efforts to develop methodologies and chemistry for the synthesis of more complex structures. The focus of this new volume is much broader, and covers not only the essential procedures for the production of linear peptides but also more advanced techniques for preparing cyclic, side-chain modified, phospho- and glycopeptides. Many other methods also deserving attention have been included: convergent peptide synthesis; peptide-protein conjugation; chemoselective ligation; and chemoselective purification. The difficult preparation of cysteine and methionine-containing peptides is also covered, as well as methods for overcoming aggregation during peptide chain assembly and a survey of available automated instrumentation.

scholarly journals Analysis of Driving Dynamics Considering Driving Resistances in On-Road Driving

Energies ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3408
Author(s):  
Jingeun Song ◽  
Junepyo Cha
Keyword(s):  
Combustion Engine ◽  
Vehicle Speed ◽  
Driving Dynamic ◽  
Engine Emissions ◽  
Engine Load ◽  
Positive Acceleration ◽  
Emission Regulations ◽  
Transportation Emissions ◽  
Light Duty Vehicles ◽  
Dynamic Variables

Internal combustion engine emissions are a serious worldwide problem. To combat this, emission regulations have become stricter with the goal of reducing the proportion of transportation emissions in global air pollution. In addition, the European Commission passed the real driving emissions–light-duty vehicles (RDE-LDV) regulation that evaluates vehicle emissions by driving on real roads. The RDE test is significantly dependent on driving conditions such as traffic or drivers. Thus, the RDE regulation has the means to evaluate driving dynamics such as the vehicle speed per acceleration (v·apos) and the relative positive acceleration (RPA) to determine whether the driving during these tests is normal or abnormal. However, this is not an appropriate way to assess the driving dynamics because the v⋅apos and the RPA do not represent engine load, which is directly related to exhaust emissions. Therefore, in the present study, new driving dynamic variables are proposed. These variables use engine acceleration calculated from wheel force instead of the acceleration calculated from the vehicle speed, so they are proportional to the engine load. In addition, a variable of driving dynamics during braking is calculated using the negative wheel force. This variable can be used to improve the accuracy of the emission assessment by analyzing the braking pattern.

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