A- and B-site doping effect on physicochemical properties of Sr2−xBaxMMoO6 (M = Mg, Mn, Fe) double perovskites — candidate anode materials for SOFCs

In this work, we evaluate the physicochemical properties of Sr[Formula: see text]BaxMMoO6 (M [Formula: see text] Mg, Mn, Fe) double perovskites as alternative anode materials for solid oxide fuel cells, for which the effect of substitution of strontium by barium in a full range of compositions is studied. The crystal structure, microstructure, characterization of transport properties (electrical conductivity, Seebeck coefficient) and oxygen content as a function of temperature, as well as chemical stability in oxidizing and reducing conditions are discussed. Fe- and Mo-containing Sr[Formula: see text]BaxFeMoO6 oxides show very high total conductivities with values of 100–1000 S[Formula: see text][Formula: see text]cm[Formula: see text], while Sr[Formula: see text]BaxMgMoO6 present good redox stability.