Adsorption of Water Vapour on a Cleavage Surface of Lithium Fluoride

1962 ◽  
Vol 1 (4) ◽  
pp. 234-234 ◽  
Author(s):  
Koreo Kinosita ◽  
Hiroomi Kojima ◽  
Hideshi Yokota
1949 ◽  
Vol 70 (1-2) ◽  
pp. 3-4
Author(s):  
Yutaka Miyahara ◽  
Isamu Sano

Author(s):  
J. D. C. McConnell

SummaryA thermogravimetric vacuum microbalance has been used to study the reaction between β-soluble anhydrite and water vapour in the temperature range 20–100° C. Equilibrium water-vapour pressures for the hydration reaction in this temperature range were determined directly and have been compared with available data obtained by Kelly, Southard, and Anderson (1941) in the temperature range 80–120° C. The kinetics of the hydration and dehydration reactions have also been studied in a series of isothermal experiments with varying water-vapour pressure. These experiments indicate that in a vapour-pressure range close to the equilibrium value very low rates for both hydration and dehydration are observed. Outside this range of vapour pressures both hydration and dehydration rates increase suddenly and show an approximately linear increase with imposed water-vapour pressure.At low temperatures (25° C) the dehydration reaction has an associated activation energy of approximately 10 kcal mole−1. In the same temperature range additional, physical adsorption of water vapour by the specimen was noted.


1995 ◽  
Vol 12 (3) ◽  
pp. 211-219 ◽  
Author(s):  
A.M. Youssef ◽  
A.A. El-Khouly ◽  
A.I. Ahmed ◽  
E.I. El-Shafey

The textural properties (surface area and porosity) of activated carbons change upon treatment with oxidizing solutions. The extent of this change is related to the strength of the oxidizing agent. Oxidation also changes the chemistry of the surface by forming carbon–oxygen groups which are the sites upon which the initial adsorption of water vapour takes place. The adsorption of water vapour at 300–320 K is mainly physical and the isosteric heat of adsorption decreases continuously as the surface coverage increases. The entropy of adsorption of water vapour on untreated and oxidized carbons, at different adsorption temperatures, has been calculated.


1962 ◽  
Vol 58 ◽  
pp. 1734 ◽  
Author(s):  
P. G. Hall ◽  
F. C. Tompkins

1976 ◽  
Vol 7 (15) ◽  
pp. no-no
Author(s):  
PETER B. BARRACLOUGH ◽  
PETER G. HALL

1946 ◽  
Vol 65 (9) ◽  
pp. 258-259 ◽  
Author(s):  
Norman F. H. Bright ◽  
Thomas Carson

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