Methane Partial Oxidation-Assisted H2O/CO2Co-Electrolysis for Syngas Production in Both Electrodes

2017 ◽  
Vol 78 (1) ◽  
pp. 3159-3166 ◽  
Author(s):  
Yaqi Wang ◽  
Minfang Han
RSC Advances ◽  
2021 ◽  
Vol 11 (37) ◽  
pp. 23095-23104
Author(s):  
Asim Riaz ◽  
Wojciech Lipiński ◽  
Adrian Lowe

Cerium doping into the V2O5 lattice forms a reversible V2O3/VO redox pair after sequential methane partial oxidation and CO2/H2O splitting reactions and produces syngas (H2, CO) with fast rates and high oxygen exchange capacity.


2018 ◽  
Vol 565 ◽  
pp. 119-126 ◽  
Author(s):  
Zhitao Wang ◽  
Yi Cheng ◽  
Xin Shao ◽  
Jean-Pierre Veder ◽  
Xun Hu ◽  
...  

Fuel ◽  
2020 ◽  
Vol 278 ◽  
pp. 118360 ◽  
Author(s):  
T.J. Siang ◽  
A.A Jalil ◽  
M.Y.S. Hamid ◽  
A.A. Abdulrasheed ◽  
T.A.T. Abdullah ◽  
...  

2018 ◽  
Vol 554 ◽  
pp. 54-63 ◽  
Author(s):  
Zhu Luo ◽  
David A. Kriz ◽  
Ran Miao ◽  
Chung-Hao Kuo ◽  
Wei Zhong ◽  
...  

2011 ◽  
Vol 14 (2) ◽  
pp. 133-139
Author(s):  
M. I. Sosa Vazquez ◽  
J. Salinas Gutierrez ◽  
D. Delgado Vigil ◽  
V. Collins-Martinez ◽  
A. Lopez Ortiz

Fe3O4-Ce0.75Zr0.25O2 (FeCZ) is an oxygen carrier material aimed to produce syngas through methane partial oxidation in absence of oxygen gas feed. The objective of the present research is to study the catalytic effect of Ni on FeCZ using an evaluation of the global kinetics (activation energy, reaction rate, order and constant) of its reaction with methane for syngas production. FeCZ and 0.05NiFeCZ (Ni/Fe = 0.05 molar ratio) were synthesized through co-precipitation of their precursor nitrate salts, while 2NiFeCZ was prepared by impregnation of FeCZ with a nickel nitrate solution to obtain a 2 %W Ni material. Samples were calcined at 950°C during 4 hours in air. Kinetic study of oxygen carriers (FeCZ, 0.05NiFeCZ and 2NiFeCZ) reduction with methane was followed through thermogravimetric analysis (TGA) at 5, 7.5 and 10% CH4/Ar and 600, 650 and 700°C. Initial reaction rate was obtained from the slope of the linear region of the weight change signal as a function of time. Results indicate a first order global reaction rate for all materials. Activation energies for samples FeCZ, 0.05NiFeCZ and 2NiFeCZ were 52.2, 39.5 and 28.3 Kcal/mol, respectively. Thus, reflecting the catalytic effect of Ni over the FeCZ global reaction rate.


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