Mechanism Leading to Irreversible Capacity Loss in Li Ion Rechargeable Batteries

1995 ◽  
Vol 142 (9) ◽  
pp. 2914-2918 ◽  
Author(s):  
Y. Matsumura ◽  
S. Wang ◽  
J. Mondori
2016 ◽  
Vol 4 (47) ◽  
pp. 18416-18425 ◽  
Author(s):  
Fu-Da Yu ◽  
Lan-Fang Que ◽  
Zhen-Bo Wang ◽  
Yin Zhang ◽  
Yuan Xue ◽  
...  

We report an effective approach to fabricate layered-spinel capped nanotube assembled 3D Li-rich hierarchitectures as a cathode material for Li-ion batteries. The resultant material exhibits a reduced first-cycle irreversible capacity loss, rapid Li-ion diffusion rate and excellent cycle stability.


1999 ◽  
Author(s):  
W. Jiang ◽  
X. Song ◽  
K. Kinoshita ◽  
T. Tran

2019 ◽  
Vol 7 (19) ◽  
pp. 11996-12007 ◽  
Author(s):  
Julija Vinckevičiūtė ◽  
Maxwell D. Radin ◽  
Nicholas V. Faenza ◽  
Glenn G. Amatucci ◽  
Anton Van der Ven

Interlayer cation migration in layered cathodes, which can lead to irreversible capacity loss, is affected by surrounding transition metals.


2017 ◽  
Vol 164 (12) ◽  
pp. A2374-A2389 ◽  
Author(s):  
Bramy Pilipili Matadi ◽  
Sylvie Geniès ◽  
Arnaud Delaille ◽  
Claude Chabrol ◽  
Eric de Vito ◽  
...  

ACS Nano ◽  
2014 ◽  
Vol 8 (7) ◽  
pp. 6701-6712 ◽  
Author(s):  
Youngjun Kim ◽  
Jung-Hyun Lee ◽  
Sungeun Cho ◽  
Yongwoo Kwon ◽  
Insik In ◽  
...  

2021 ◽  
Vol 6 (3) ◽  
pp. 26
Author(s):  
Bernardo Barbiellini ◽  
Jan Kuriplach ◽  
Rolando Saniz

Improving the efficiency and longevity of energy storage systems based on Li- and Na-ion rechargeable batteries presents a major challenge. The main problems are essentially capacity loss and limited cyclability. These effects are due to a hierarchy of factors spanning various length and time scales, interconnected in a complex manner. As a consequence, and in spite of several decades of research, a proper understanding of the ageing process has remained somewhat elusive. In recent years, however, combinations of advanced spectroscopy techniques and first-principles simulations have been applied with success to tackle this problem. In this Special Issue, we are pleased to present a selection of articles that, by precisely applying these methods, unravel key aspects of the reduction–oxidation reaction and intercalation processes. Furthermore, the approaches presented provide improvements to standard diagnostic and characterisation techniques, enabling the detection of possible Li-ion flow bottlenecks causing the degradation of capacity and cyclability.


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