Thermodynamics of Molten Silver Chloride-Alkali Chloride Solutions by Electromotive Force Measurements

1970 ◽  
Vol 117 (9) ◽  
pp. 1130 ◽  
Author(s):  
A. D. Pelton ◽  
S. N. Flengas

1983 ◽  
Vol 61 (10) ◽  
pp. 2344-2348 ◽  
Author(s):  
Hamed Bahri ◽  
Jean-Claude Hallé ◽  
Robert Schaal

Electromotive force measurements of cells without liquid-junction containing hydrogen electrodes and silver – silver chloride electrodes have been used to derive the dissociation constants of acetic acid and solvent water – ethylene glycol mixtures (50 and 70 mass % of ethyleneglycol) at 14 temperatures from −35 to 30 °C. Primary acidity standards related to these acetic buffered and sodium hydroxide solutions are given.





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