Influence of Ionomer Content on Both Cell Performance and Load Cycle Durability for Polymer Electrolyte Fuel Cells Using Pt/Nb-SnO2 Cathode Catalyst Layers

2018 ◽  
Vol 165 (15) ◽  
pp. J3083-J3089 ◽  
Author(s):  
Katsuyoshi Kakinuma ◽  
Ryo Kobayashi ◽  
Akihiro Iiyama ◽  
Makoto Uchida
2008 ◽  
Vol 86 (7) ◽  
pp. 657-667 ◽  
Author(s):  
Zetao Xia ◽  
Qianpu Wang ◽  
Michael Eikerling ◽  
Zhongsheng Liu

In this work, we analyze effectiveness factors of Pt utilization in perfluorosulfonate ionomer (PFSI) bonded thin film cathode catalyst layers of polymer electrolyte fuel cells. We define the effectiveness factor of Pt utilization as the apparent rate of current conversion exhibited by a specific catalyst layer design divided by the ideal rate obtained if all Pt atoms were used equally in electrochemical reactions at the specified electrode overpotential and externally provided reactant concentrations. This definition includes statistical factors at all relevant scales as well as non-uniformities of reaction rate distributions under operation. Our model is based on the random composite agglomerated morphology of the catalyst layer. It accounts for the interplay of transport phenomena and electrochemical kinetics. At the mesoscopic scale, limited effectiveness of Pt utilization in agglomerates is mainly an electrostatic effect. We determined spatial distributions of effectiveness factors of agglomerates in the through-plane direction, and thereafter calculated overall effectiveness factors of the cathode catalyst layer. Our results show that small agglomerate radius, low operating current density, high operating temperature, and high oxygen partial pressure result in high effectiveness factors of Pt utilization. Finally, we compared PFSI-bonded thin film cathode catalyst layers with ultrathin two-phase cathode catalyst layers in terms of effectiveness factors. Including the surface to volume atom ratio of Pt nanoparticles, the two different types of structures exhibit similar effectiveness factors of Pt utilization, which are found to be distinctly below 10%.Key words: polymer electrolyte fuel cells, fuel cell modeling, cathode catalyst layer, Pt utilization, effectiveness factor.


2005 ◽  
Vol 152 (6) ◽  
pp. A1171 ◽  
Author(s):  
Zhong Xie ◽  
Titichai Navessin ◽  
Ken Shi ◽  
Robert Chow ◽  
Qianpu Wang ◽  
...  

2004 ◽  
Vol 151 (7) ◽  
pp. A950 ◽  
Author(s):  
Qianpu Wang ◽  
Michael Eikerling ◽  
Datong Song ◽  
Zhongsheng Liu ◽  
Titichai Navessin ◽  
...  

2011 ◽  
Vol 56 (25) ◽  
pp. 9064-9073 ◽  
Author(s):  
Sung-Dae Yim ◽  
Young-Jun Sohn ◽  
Seok-Hee Park ◽  
Young-Gi Yoon ◽  
Gu-Gon Park ◽  
...  

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