Mitigation of PtCo/C Cathode Catalyst Degradation via Control of Relative Humidity

Maintaining the high performance of proton-exchange membrane fuel cells (PEMFC) over the course of its lifetime is a key enabling factor for its successful commercialization as a primary power source in zero-emission transportation applications. In this context, it is important to mitigate the degradation of PtCo-alloy based cathode catalysts used for oxygen reduction reaction (ORR). PtCo-alloy catalysts exhibit high activity at beginning-of-life (BOL) which tends to decrease during operation due to loss of electrochemical surface area (ECSA) and dissolution-contamination related effects of the Co-alloying component. Here, we demonstrate the use of relative humidity (RH) of the inlet gases as a controllable parameter to mitigate the degradation of PtCo-alloy catalyst degradation. We employ a catalyst-specific voltage cycling accelerated stress test (AST) durability protocol as a function of inlet RH to degrade PtCo catalysts. A series of in situ electrochemical diagnostics and ex situ characterizations have been carried out to investigate the catalyst layer characteristics at end-of-test (EOT). Our results show that at sub-saturated conditions of durability protocol operation, PtCo catalyst sustains higher EOT H2/air performance due to better retention of ECSA and smaller impact of Co2+ dissolution/contamination.

Hollow PtCo alloy nanospheres as a high-Z and oxygen generating nanozyme for radiotherapy enhancement in non-small cell lung cancer

Radiotherapy, as well as chemotherapy and surgery, occupies an essential position in the tumor treatment. Nonetheless, insufficient radiation deposition and hypoxia-related radioresistance of the cancer still leave serious challenges in...

Erratum: Wang, D., et al. Self-Assembly Synthesis of the MoS2/PtCo Alloy Counter Electrodes for High-Efficiency and Stable Low-Cost Dye-Sensitized Solar Cells. Nanomaterials 2020, 10, 1725

There is an error in the Funding statement of [...]

Self-Assembly Synthesis of the MoS2/PtCo Alloy Counter Electrodes for High-Efficiency and Stable Low-Cost Dye-Sensitized Solar Cells

In this work, MoS2 microspheres/PtCo-alloy nanoparticles (MoS2/PtCo-alloy NPs) were composited via a novel and facile process which MoS2 is functionalized by poly (N-vinyl-2-pyrrolidone) (PVP) and self-assembled with PtCo-alloy NPs. This new composite shows excellent electrocatalytic activity and great potential for dye-sensitized solar cells (DSSCs) as a counter electrode (CE) material. Benefiting from heterostructure and synergistic effects, the MoS2/PtCo-alloy NPs exhibit high electrocatalytic activity, low charge-transfer resistance and stability in the cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) test. Meanwhile, a high power-conversion efficiency (PCE) of 8.46% is achieved in DSSCs with MoS2/PtCo-alloy NP CEs, which are comparable to traditional Pt CEs (8.45%). This novel composite provides a new high-performance, stable and cheap choice for CEs in DSSCs.

PtMn/PtCo alloy nanofascicles: robust electrocatalysts for electrocatalytic hydrogen evolution reaction under both acidic and alkaline conditions

Herein, PtMn and PtCo nanofascicles were prepared by ultrathin nanofibers using a versatile method, and can be employed as effective electrocatalysts toward the HER under both acidic and alkaline conditions.

Highly stable and ordered intermetallic PtCo alloy catalyst supported on graphitized carbon containing Co@CN for oxygen reduction reaction

Ordered intermetallic PtCo synthesized from N-doped graphitic carbon-containing Co presents the high durability with low Pt loading after 30 000 load-simulated cycles in proton exchange membrane fuel cells.