Crystal Structure and Proton Conductivity in BaSn1-xScxO3-δ (x = 0-0.5)

2021 ◽  
Author(s):  
Artem A. Babaryk ◽  
Alaa Adawy ◽  
Inés García ◽  
Camino Trobajo ◽  
Zakariae Amghouz ◽  
...  

Although the fibrous polymorphic modification of titanium phosphate, π-Ti2O(PO4)2·2H2O (π-TiP) is known for decades, its crystal structure has remained unsolved. Herewith we report the crystal structure of π-TiP at a...


2008 ◽  
Vol 91 (9) ◽  
pp. 3039-3044 ◽  
Author(s):  
Istaq Ahmed ◽  
Maths Karlsson ◽  
Sten-Gunnar Eriksson ◽  
Elisabet Ahlberg ◽  
Christopher S. Knee ◽  
...  

2005 ◽  
Vol 41 (1) ◽  
pp. 69-72 ◽  
Author(s):  
N. N. Chudinova ◽  
E. V. Murashova ◽  
A. B. Ilyukhin ◽  
V. A. Tarnopol?skii ◽  
A. B. Yaroslavtsev

2009 ◽  
Vol 38 (7) ◽  
pp. 654-655 ◽  
Author(s):  
Shota Morikawa ◽  
Teppei Yamada ◽  
Hiroshi Kitagawa

1979 ◽  
Vol 34 (5) ◽  
pp. 750-751 ◽  
Author(s):  
Rüdiger Kniep ◽  
Axel Wilms

The crystal structure of the phase Al2O3 · 2 P2O5 · 9 H2O contains two different structural units: isolated PO4 tetrahedra and larger aggregates consisting of two AlO6 octahedra connected with three PO4 tetrahedra by common vertices. Location of hydrogen positions failed. Interpretation of bond distances and molecular symmetry leads to a structural formula [Al2(H1+xPO4)3(H2O)6](H3-3xPO4); 0 ≦ x ≦ 1indicating proton disorder. Proton conductivity seems to be possible.


2021 ◽  
Vol 340 ◽  
pp. 01041
Author(s):  
Rostislav Gus’kov ◽  
Valentina Ponomareva

Hybrid polymer compounds (1–х)CsH5(PO4)2-хButvar (х=0– 0.3), synthesized with different solvents (ethanol and isopropanol) were first synthesized and investigated. Fundamental possibility of creating new highly conductive thin polymer electrolytes based on CsH5(PO4)2 was shown. An optimal synthesis method was determined. The crystal structure of CsH5(PO4)2 (P21/c) remains unchanged in the polymer system. The thickness of the electrolyte is no more than 50-100 μm. Proton conductivity increases by 2 orders of magnitude and depends on the composition. The highest conductivity was 10-1 S/cm at 135 °C. Changes in conductivity are caused by dispersion of the salt, as well as by the presence of insignificant amounts of residual water under the synthesis conditions.


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