scholarly journals High Pressure Synthesis and Electrochemical Properties of Lithium Transition Metal Oxides with a Layered Rocksalt Structure

2012 ◽  
2014 ◽  
Vol 70 (a1) ◽  
pp. C755-C755
Author(s):  
Youwen Long

ABO3-type perovskite oxides exhibit a wide variety of interesting physical properties such as superconductivity, colossal magnetoresistance, multiferroic behavior etc. For a simple ABO3 perovskite, if three quarters of the A site is replaced by a transition metal A', then the so-called A-site ordered double perovskite with the chemical formula of AA'3B4O12 can form. Since both A' and B sites accommodate transition metal ions, in addition to conventional B-B interaction, the new A'-A' and/or A'-B interaction is possible to show up, giving rise to the presence of many novel physical properties. Here we will show our recent research work on the high-pressure synthesis of several A-site ordered perovskites as well as a series of interesting physical properties like temperature- and pressure-induced intermetallic charge transfer, negative thermal expansion, magnetoelectric coupling multiferroic and so on. [1-3]


2016 ◽  
Vol 94 (15) ◽  
Author(s):  
I. Leonov ◽  
L. Pourovskii ◽  
A. Georges ◽  
I. A. Abrikosov

Author(s):  
Elena Solana-Madruga ◽  
Clemens Ritter ◽  
Olivier Mentré ◽  
Ángel M. Arévalo-López

The transition-metal-only Mn3MnTa2O9 triple perovskite structure with 1 : 2 B-site order has been prepared by high pressure synthesis. It shows a complex modulated magnetic structure and a 25% band gap reduction from its room pressure polymorph.


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