Studies of Earth Abundant Metal Complexes for Near Neutral Aqueous Redox Flow Battery (RFB) for Grid Storage

Here, we outline some basic pitfalls in the electrochemical investigation of aqueous metal complexes, advocate for the use of bulk electrolysis in redox flow cells for electrolyte analysis, and demonstrate methods of operation and performance of a lab scale redox flow battery.

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Studies on Metal Complexes as Active Materials in Redox-flow Battery Using Ionic Liquids as Electrolyte: Electrochemical Properties of [Fe(L)x][Tf2N]2 (L: Multidentate Ligands, x = 2 or 3) in 1-Butyl-3-methylimidazolium Bis(Trifluoromethylsulfonyl)Imide, [BMI][Tf2N]

Electrochemistry ◽

10.5796/electrochemistry.82.566 ◽

2014 ◽

Vol 82 (7) ◽

pp. 566-572 ◽

Cited By ~ 10

Author(s):

Kazunori TERAMOTO ◽

Toshikazu NISHIDE ◽

Shin OKUMURA ◽

Koichiro TAKAO ◽

Yasuhisa IKEDA

Keyword(s):

Ionic Liquids ◽

Metal Complexes ◽

Electrochemical Properties ◽

Redox Flow Battery ◽

Multidentate Ligands ◽

Flow Battery ◽

Active Materials

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Kinetics study of transition metal complexes (Ce–DTPA, Cr–DTPA and V–DTPA) for redox flow battery applications

Electrochimica Acta ◽

10.1016/j.electacta.2013.01.081 ◽

2013 ◽

Vol 94 ◽

pp. 336-343 ◽

Cited By ~ 13

Author(s):

Portia Modiba ◽

Mangaka Matoetoe ◽

Andrew M. Crouch

Keyword(s):

Transition Metal ◽

Metal Complexes ◽

Transition Metal Complexes ◽

Kinetics Study ◽

Redox Flow Battery ◽

Flow Battery

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Studies on Metal Complexes as Active Materials in Redox-flow Battery Using Ionic Liquids as Electrolyte: Cyclic Voltammetry of Betainium Bis(Trifluoromethylsulfonyl)Imide Solution Dissolving Na[FeIII(edta)(H2O)] as an Anode Active Material

Electrochemistry ◽

10.5796/electrochemistry.83.730 ◽

2015 ◽

Vol 83 (9) ◽

pp. 730-732 ◽

Cited By ~ 1

Author(s):

Kazunori TERAMOTO ◽

Toshikazu NISHIDE ◽

Yasuhisa IKEDA

Keyword(s):

Cyclic Voltammetry ◽

Ionic Liquids ◽

Metal Complexes ◽

Active Material ◽

Redox Flow Battery ◽

Flow Battery ◽

Active Materials ◽

Anode Active Material

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A two-dimensional mathematical model for vanadium redox flow battery stacks incorporating nonuniform electrolyte distribution in the flow frame

Applied Thermal Engineering ◽

10.1016/j.applthermaleng.2019.02.037 ◽

2019 ◽

Vol 151 ◽

pp. 495-505 ◽

Cited By ~ 3

Author(s):

B.W. Zhang ◽

Y. Lei ◽

B.F. Bai ◽

A. Xu ◽

T.S. Zhao

Keyword(s):

Mathematical Model ◽

Vanadium Redox Flow Battery ◽

Two Dimensional ◽

Redox Flow Battery ◽

Flow Battery ◽

Vanadium Redox

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A cobalt sulfide cluster-based catholyte for aqueous flow battery applications

Journal of Materials Chemistry A ◽

10.1039/c8ta05788e ◽

2018 ◽

Vol 6 (44) ◽

pp. 21927-21932 ◽

Cited By ~ 7

Author(s):

Matthew B. Freeman ◽

Le Wang ◽

Daniel S. Jones ◽

Christopher M. Bejger

Keyword(s):

Active Material ◽

Water Soluble ◽

Molecular Cluster ◽

Cobalt Sulfide ◽

Redox Flow Battery ◽

Flow Battery ◽

Aqueous Flow ◽

Sulfide Cluster

A water-soluble Co6S8 molecular cluster was prepared and electrochemically analyzed as a potential active material for redox flow battery applications.

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