Analysis of Oxide Film on Aluminum Electrode in Ionic Liquid Based Aluminum-Air Battery

2019 ◽  
Keyword(s):  
Ionic Liquid ◽  
Oxide Film ◽  
Aluminum Electrode ◽  
Air Battery

Aluminum–air battery based on an ionic liquid electrolyte

2014 ◽  
Vol 2 (47) ◽  
pp. 20237-20242 ◽  
Author(s):  
D. Gelman ◽  
B. Shvartsev ◽  
Y. Ein-Eli
Keyword(s):  
Ionic Liquid ◽  
Room Temperature ◽  
Liquid Electrolyte ◽  
Room Temperature Ionic Liquid ◽  
Ionic Liquid Electrolyte ◽  
Current Densities ◽  
Air Battery

This study presents a novel non-aqueous Al–air battery utilizing 1-ethyl-3-methylimidazolium oligo-fluoro-hydrogenate room temperature ionic liquid. The Al–air-RTIL system can sustain current densities up to 1.5 mA cm−2, producing capacities above 140 mA h cm−2, thus utilizing above 70% of the theoretical Al capacity.

scholarly journals Suppression of byproduct accumulation in rechargeable aluminum–air batteries using non-oxide ceramic materials as air cathode materials

2017 ◽  
Vol 1 (5) ◽  
pp. 1082-1089 ◽  
Author(s):  
Ryohei Mori
Keyword(s):  
Ionic Liquid ◽  
Cathode Materials ◽  
High Capacity ◽  
Ceramic Materials ◽  
Electrochemical Reactions ◽  
Oxide Ceramic ◽  
Air Cathode ◽  
Air Battery ◽  
Charge Discharge

To develop a high-capacity rechargeable aluminum–air battery with resistance toward the degradation induced by long-term charge–discharge electrochemical reactions, non-oxide ceramic materials, e.g., TiN, TiC, and TiB2, were used as air cathode materials with the ionic liquid 1-ethyl-3-methylimidazolium chloride as the electrolyte.

Evaluation and analysis of Li-air battery using ether-functionalized ionic liquid

2013 ◽  
Vol 240 ◽  
pp. 14-17 ◽  
Author(s):  
Shougo Higashi ◽  
Yuichi Kato ◽  
Kensuke Takechi ◽  
Hirofumi Nakamoto ◽  
Fuminori Mizuno ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Functionalized Ionic Liquid ◽  
Air Battery

An Electrically Rechargeable Al-Air Battery with Aprotic Ionic Liquid Electrolyte

2017 ◽  
Vol 75 (22) ◽  
pp. 85-92 ◽  
Author(s):  
Nicky Bogolowski ◽  
Jean-Francois Drillet
Keyword(s):  
Ionic Liquid ◽  
Liquid Electrolyte ◽  
Ionic Liquid Electrolyte ◽  
Air Battery

scholarly journals In search of an appropriate ionic liquid as electrolyte for macroporous manganese oxide film electrochemistry

2013 ◽  
Vol 239 ◽  
pp. 1-8 ◽  
Author(s):  
Tânia M. Benedetti ◽  
Vinicius R. Gonçales ◽  
Susana I. Córdoba de Torresi ◽  
Roberto M. Torresi
Keyword(s):  
Ionic Liquid ◽  
Oxide Film ◽  
Manganese Oxide

Study of a Li–air battery having an electrolyte solution formed by a mixture of an ether-based aprotic solvent and an ionic liquid

2012 ◽  
Vol 213 ◽  
pp. 233-238 ◽  
Author(s):  
Laura Cecchetto ◽  
Mark Salomon ◽  
Bruno Scrosati ◽  
Fausto Croce
Keyword(s):  
Ionic Liquid ◽  
Electrolyte Solution ◽  
Aprotic Solvent ◽  
Air Battery

scholarly journals Room-Temperature Preparation of Ta Ions-Containing Ionic Liquid and its Vapor Deposition toward Ta-Oxide Film Coating

2022 ◽  
Author(s):  
Nana Hozuki ◽  
Kenichi Kaminaga ◽  
Shingo Maruyama ◽  
Daisuke Shiga ◽  
Hiroshi Kumigashira ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Oxide Film ◽  
Room Temperature ◽  
Film Coating ◽  
Metal Plate ◽  
Photoemission Spectroscopy ◽  
X Ray ◽  
Vacuum Forming ◽  
Order Of Magnitude ◽  
Temperature Preparation

Abstract Ta ions-containing solutions, which are brown in color with no precipitation, were successfully prepared through an electroelution process with ionic liquid (IL). An as-delivered Ta metal plate covered with a passivation oxide film could be easily eluted even at room temperature by simply applying an anodic potential of, e.g. +2.2 V vs. Ag in [Bmim][PF6] IL. According to the quantity of electric charge required for oxidation of Ta, most Ta ions in the IL were suggested to be in an oxidation state of +5, which was also confirmed by x-ray photoemission spectroscopy (XPS). Ta ions in IL were found to thermally evaporate together with IL molecules by heating in a vacuum, forming a deposit of the Ta ions-containing IL on a substrate. The Ta concentrations in the deposits were reduced uniquely by about one order of magnitude from those in the original bulk source through the evaporation process under the present conditions. Furthermore, a possibility of the formation of thin film-like Ta oxide from such a Ta ions-containing IL deposit and its bulk droplet prepared on substrates by annealing in air at 1000oC will be discussed.

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