scholarly journals Morphology and Magnetic Properties of Ferriferous Two-Phase Sodium Borosilicate Glasses

2014 ◽  
Vol 2014 ◽  
pp. 1-7 ◽  
Author(s):  
Alexander Naberezhnov ◽  
Nadezda Porechnaya ◽  
Viktor Nizhankovskii ◽  
Alexey Filimonov ◽  
Bernard Nacke

This contribution is devoted to the study of morphology and magnetic properties of sodium borosilicate glasses with different concentrations (15, 20, and 25 wt.%) ofα-Fe2O3in an initial furnace charge. These glasses were prepared by a melt-quenching method. For all glasses a coexistence of drop-like and two-phase interpenetrative structures is observed. The most part of a drop structure is formed by self-assembling iron oxides particles. All types of glasses demonstrate the magnetic properties and can be used for preparation of porous magnetic matrices with nanometer through dendrite channel structure.

2020 ◽  
Vol 46 (8) ◽  
pp. 808-811
Author(s):  
S. A. Borisov ◽  
A. A. Naberezhnov ◽  
B. Nacke ◽  
A. Nikanorov

Author(s):  
С.А. Борисов ◽  
А.А. Набережнов ◽  
B. Nacke ◽  
A. Nikanorov

The magnetic properties of two-phase borosilicate glasses containing in the skeleton a mixture of β-Fe2O3 and Fe3O4 nanoparticles have been studied. The sizes of nanoparticles have been determined, the value of blocking temperature (TB ~ 330 K) for ensemble of superparamagnetic nanoparticles is obtained. It is shown that in the high applied magnetic fields the specific magnetization of these glasses increases sharply at approaching and below Neel temperature for the bulk β-Fe2O3.


2017 ◽  
Vol 2017 ◽  
pp. 1-9
Author(s):  
N. Andreeva ◽  
M. Tomkovich ◽  
A. Naberezhnov ◽  
B. Nacke ◽  
A. Filimonov ◽  
...  

The morphology and composition of four types of two-phase alkali borosilicate glasses with magnetic atoms prepared by inductive melting have been studied. The results of scanning electron microscopy point to uniform distribution of Na, Si, and O atoms in these samples while magnetic iron atoms form ball-shaped agglomerates. The magnetic properties of these agglomerates have been confirmed by magnetic force microscopy. Atomic force microscopy had shown that in these samples two different morphological structures, drop-like and dendrite net, are formed. The formation of dendrite-like structure is a necessary condition for production of porous magnetic glasses. The obtained results allow us to optimize the melting and heat treatment processes leading to production of porous alkali borosilicate glasses with magnetic properties. The first results for nanocomposite materials on the basis of magnetic glasses containing the embedded ferroelectrics KH2PO4 demonstrate the effect of applied magnetic field on the ferroelectric phase transition.


2017 ◽  
Vol 6 (3) ◽  
pp. 251-261 ◽  
Author(s):  
V. Sandu ◽  
E. Cimpoiasu ◽  
A. Kuncser ◽  
M. S. Nicolescu

2014 ◽  
Vol 2014 ◽  
pp. 1-5 ◽  
Author(s):  
R. Ruamnikhom ◽  
P. Limsuwan ◽  
M. Horprathum ◽  
N. Chanthima ◽  
H. J. Kim ◽  
...  

Physical, optical, and luminescence properties of Nd3+ions in bismuth barium borate glass system were studied. The glasses prepared by a melt quenching method were doped at various Nd2O3concentrations in compositions (40-x)B2O3 : 40Bi2O3 : 20BaO : xNd2O3(wherex= 0.00, 0.50, 1.00, 1.50, 2.00, and 2.50 in mol%). Luminescence properties of the glasses were studied under two excitations of 585 and 750 nm for downconversion. From both excitations, the results show emission bands in NIR region corresponding to the transitions between4F3/2 → 4I9/2(900 nm),4F3/2 → 4I11/2(1,060 nm), and4F3/2 → 4I13/2(1,345 nm). The luminescence intensity obtained with 585 nm excitation was stronger than 750 nm, with the strongest NIR emission at 1,060 nm. The upconversion emission spectrum exhibits strong fluorescence bands in the UV region at 394 nm (λex=591 nm). The processes are associated with excited state absorption (ESA) from4F3/2level to4D3/2level and it is the radiative decay from the4D3/2to ground levels (4D3/2 → 4I13/2) which are responsible for the emission at 394 nm.


Author(s):  
Yunman Lee ◽  
Jae-kyun Jeon ◽  
Hyemin Shin ◽  
Jae-yong Kim

AbstractQuasicrystals made with Ti, Zr and Ni are good candidate materials studying the magnetic properties of aperiodic structure because the role of Ni in stabilization of the quasicrystal phase is important. Various magnetic states in quasicrystals have been reported including diamagnetism, paramagnetism, spin glass, ferromagnetism and ferrimagnetism. We prepared Ti–Zr–Ni quasicrystals by rapid quenching method. The magnetization (


2010 ◽  
Vol 168-169 ◽  
pp. 169-172
Author(s):  
Tatiana A. Denisova ◽  
Lidia G. Maksimova ◽  
Dina G. Kellerman ◽  
M.A. Melkozerova ◽  
Elena V. Zabolotskaya ◽  
...  

The results of magnetic behavior study of nickel ions, which were introduced into Zn2Fe(CN)6∙5.5H2O with channel structure, are presented. It was shown that nickel cations replace a part of Zn2+ ions or locate in the channels of lattice via the molecular mechanism sorption. It is shown that the magnetic moments μNi of the sorption products strongly depend on the content of Ni2+ ions. The values of μNi of the samples with Ni/Fe(CN)6=2.26 and 2.86 are great ~ 3.9 and 4.4 μB respectively and close to the value typical of free Ni2+ ions μ =4.47μB.


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