Photophysical behavior of Ru(II) and Os(II) terpyridyl phenylene vinylene complexes: perturbation of MLCT state by intra-ligand charge-transfer state

2007 ◽  
Vol 33 (1-2) ◽  
pp. 63-77 ◽  
Author(s):  
Xian -Yong Wang ◽  
Andre Guerzo ◽  
Hari Tunuguntla ◽  
Russell H. Schmehl
Keyword(s):  
Charge Transfer ◽  
Charge Transfer State ◽  
Phenylene Vinylene ◽  
Ligand Charge Transfer ◽  
Photophysical Behavior ◽  
Mlct State ◽  
Transfer State

Detailed Description of the Metal-to-Ligand Charge-Transfer State in Monoterpyridine IrIII Complexes

2009 ◽  
Vol 2009 (14) ◽  
pp. 2067-2073 ◽  
Author(s):  
Naokazu Yoshikawa ◽  
Shinichi Yamabe ◽  
Nobuko Kanehisa ◽  
Tsuyoshi Inoue ◽  
Hiroshi Takashima ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Charge Transfer State ◽  
Ligand Charge Transfer ◽  
Transfer State

Photooxidation of Dicyanoaurate(I) Induced by Metal-to-Ligand Charge Transfer Excitation

1998 ◽  
Vol 53 (8) ◽  
pp. 853-855 ◽  
Author(s):  
Horst Kunkely ◽  
Arad Vogler
Keyword(s):  
Electron Transfer ◽  
Excited State ◽  
Charge Transfer ◽  
Charge Transfer State ◽  
State Electron ◽  
Ligand Charge Transfer ◽  
Charge Transfer Excitation ◽  
Transfer State

Abstract The irradiation of [Au(CN)2]- in oxygen-saturated acetonitrile leads to photooxidation of Au(I). In the presence of additional chloride [Au(CN)2CL2]- is formed with φ= 0.5 x 10-4 at λirr = 254 nm. It is assumed that [Au(CN)2]- in its metal-to-ligand charge transfer state undergoes an excited state electron transfer to oxygen in the primary photochemical step.

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