scholarly journals Effects of CsSnxPb1−xI3 Quantum Dots as Interfacial Layer on Photovoltaic Performance of Carbon-Based Perovskite Solar Cells

2021 ◽  
Vol 16 (1) ◽  
Author(s):  
Chi Zhang ◽  
Zhiyuan He ◽  
Xuanhui Luo ◽  
Rangwei Meng ◽  
Mengwei Chen ◽  
...  

AbstractIn this work, inorganic tin-doped perovskite quantum dots (PQDs) are incorporated into carbon-based perovskite solar cells (PSCs) to improve their photovoltaic performance. On the one hand, by controlling the content of Sn2+ doping, the energy level of the tin-doped PQDs can be adjusted, to realize optimized band alignment and enhanced separation of photogenerated electron–hole pairs. On the other hand, the incorporation of tin-doped PQDs provided with a relatively high acceptor concentration due to the self-p-type doping effect is able to reduce the width of the depletion region near the back surface of the perovskite, thereby enhancing the hole extraction. Particularly, after the addition of CsSn0.2Pb0.8I3 quantum dots (QDs), improvement of the power conversion efficiency (PCE) from 12.80 to 14.22% can be obtained, in comparison with the pristine device. Moreover, the experimental results are analyzed through the simulation of the one-dimensional perovskite/tin-doped PQDs heterojunction.

2021 ◽  
Author(s):  
Chi Zhang ◽  
Zhiyuan He ◽  
Xuanhui Luo ◽  
Rangwei Meng ◽  
Mengwei Chen ◽  
...  

Abstract In this work, inorganic tin-doped perovskite quantum dots (PQDs) are incorporated into carbon-based perovskite solar cells (PSCs) to improve their photovoltaic performance. On the one hand, by controlling the content of Sn2+ doping, the energy level of the tin-doped PQDs can be adjusted, to realize optimized band alignment and enhanced separation of photogenerated electron-hole pairs. On the other hand, the incorporation of tin-doped PQDs provided with a relatively high acceptor concentration due to the self-p-type doping effect, is able to reduce the width of the depletion region near the back surface of the perovskite, thereby enhancing the hole extraction. Especially, after the addition of CsSn0.2Pb0.8I3 QDs, improvement of the power conversion efficiency (PCE) from 12.80% to 14.22% can be obtained, in comparison to the pristine device. Moreover, the experimental results are analyzed through the simulation of the one-dimensional perovskite/tin-doped PQDs heterojunction.


2016 ◽  
Vol 8 (4) ◽  
pp. 347-357 ◽  
Author(s):  
Chenxi Zhang ◽  
Yudan Luo ◽  
Xiaohong Chen ◽  
Yiwei Chen ◽  
Zhuo Sun ◽  
...  

2021 ◽  
pp. 150470
Author(s):  
Shuhan Li ◽  
Yang Li ◽  
Ke Liu ◽  
Mengwei Chen ◽  
Weidong Peng ◽  
...  

2020 ◽  
Vol 8 (48) ◽  
pp. 26098-26108
Author(s):  
Shuguang Zhang ◽  
Young Jun Yoon ◽  
Xun Cui ◽  
Yajing Chang ◽  
Meng Zhang ◽  
...  

The photovoltaic performance of perovskite solar cells is enhanced by interfacing with rationally designed CsPbBrxI3−x quantum dots.


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