Hysteresis in the electrical resistivity of partially saturated sandstones

Geophysics ◽  
1991 ◽  
Vol 56 (12) ◽  
pp. 2139-2147 ◽  
Author(s):  
Rosemary Knight
Keyword(s):  
Electrical Resistivity ◽  
Unsaturated Zone ◽  
Geophysical Data ◽  
Fluid Distribution ◽  
Water Interface ◽  
Pore Scale ◽  
Laboratory Measurements ◽  
Partially Saturated ◽  
Air Water Interface ◽  
Saturation History

Laboratory measurements of the resistivity of three sandstone samples collected during imbibition (increasing Sw) and drainage (decreasing Sw) show pronounced hysteresis in resistivity throughout much of the saturation range. The variation in resistivity can be related to changes in pore‐scale fluid distribution caused by changes in saturation history. The form of the hysteresis is such that resistivity measured during imbibition is consistently less than that measured, at the same saturation, during drainage. This can be attributed to the presence of conduction at the air/water interface in partially saturated samples; an effect that is enhanced by fluid geometries associated with the imbibition process. The results of this study suggest that the dependence of geophysical data on saturation history should be considered when interpreting data from the unsaturated zone.

Pore-scale fluid distributions determined by nuclear magnetic resonance spectra of partially saturated sandstones

Geophysics ◽  
2019 ◽  
Vol 84 (3) ◽  
pp. MR107-MR114 ◽  
Author(s):  
Chunhui Fang ◽  
Baozhi Pan ◽  
Yanghua Wang ◽  
Ying Rao ◽  
Yuhang Guo ◽  
...  
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Water Saturation ◽  
Acoustic Property ◽  
P Wave ◽  
Distribution Model ◽  
Fluid Distribution ◽  
Pore Scale ◽  
Saturation Model ◽  
Partially Saturated ◽  
P Wave Velocity

The acoustic property and the P-wave velocity of partially saturated rocks depend not only on the water saturation but also on the pore-scale fluid distribution. Here, we analyzed the pore-scale fluid distribution using nuclear magnetic resonance (NMR) [Formula: see text] spectra, which present the variation of porosity components associated with NMR transverse relaxation time [Formula: see text]. Based on the [Formula: see text] spectra, we classified the pore-scale fluid distribution during water imbibition and drainage into three models: a low-saturation model, a patchy distribution model, and a uniform distribution model. We specifically assigned the low-saturation model to deal with the acoustic property of the rocks at the imbibition starting stage and the drainage final stage because cement softening has a nonnegligible effect. We studied the acoustic properties of sandstone rocks with various pore-scale fluid distributions, at the imbibition process and the drainage process. We confirmed that, once the variations in water saturation and pore-scale fluid distribution are taken into account, the P-wave velocity prediction matches well with the laboratory measurement of samples, representing nearly tight sandstone rocks that are partially saturated with distilled water.

scholarly journals Pore-Scale Investigation of Colloid Retention and Mobilization in the Presence of a Moving Air-Water Interface

2011 ◽  
Vol 10 (4) ◽  
pp. 1250-1260 ◽  
Author(s):  
Volha Lazouskaya ◽  
Lian-Ping Wang ◽  
Hui Gao ◽  
Xiaoyan Shi ◽  
Kirk Czymmek ◽  
...  
Keyword(s):  
Water Interface ◽  
Pore Scale ◽  
Air Water Interface ◽  
Colloid Retention

Sampling and analysis of the air-water interface with SEM and EDS of microlayers

1989 ◽  
Vol 47 ◽  
pp. 1004-1005
Author(s):  
Randall W. Smith ◽  
John Dash
Keyword(s):  
Heavy Metals ◽  
Surface Microlayer ◽  
Surface Films ◽  
Water Interface ◽  
Physical Processes ◽  
Infrared Spectroscopic Analysis ◽  
Eds Analysis ◽  
Air Water Interface ◽  
Significant Area ◽  
Bulk Chemical

The structure of the air-water interface forms a boundary layer that involves biological ,chemical geological and physical processes in its formation. Freshwater and sea surface microlayers form at the air-water interface and include a diverse assemblage of organic matter, detritus, microorganisms, plankton and heavy metals. The sampling of microlayers and the examination of components is presently a significant area of study because of the input of anthropogenic materials and their accumulation at the air-water interface. The neustonic organisms present in this environment may be sensitive to the toxic components of these inputs. Hardy reports that over 20 different methods have been developed for sampling of microlayers, primarily for bulk chemical analysis. We report here the examination of microlayer films for the documentation of structure and composition.Baier and Gucinski reported the use of Langmuir-Blogett films obtained on germanium prisms for infrared spectroscopic analysis (IR-ATR) of components. The sampling of microlayers has been done by collecting fi1ms on glass plates and teflon drums, We found that microlayers could be collected on 11 mm glass cover slips by pulling a Langmuir-Blogett film from a surface microlayer. Comparative collections were made on methylcel1ulose filter pads. The films could be air-dried or preserved in Lugol's Iodine Several slicks or surface films were sampled in September, 1987 in Chesapeake Bay, Maryland and in August, 1988 in Sequim Bay, Washington, For glass coverslips the films were air-dried, mounted on SEM pegs, ringed with colloidal silver, and sputter coated with Au-Pd, The Langmuir-Blogett film technique maintained the structure of the microlayer intact for examination, SEM observation and EDS analysis were then used to determine organisms and relative concentrations of heavy metals, using a Link AN 10000 EDS system with an ISI SS40 SEM unit. Typical heavy microlayer films are shown in Figure 3.

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