scholarly journals Direct Measurement of the Interaction Energy between Solids and Gases. III. Comparison of the Calorimetric Titration Method with the Amine Titration Method for the Determination of Acid Strength Distribution of Silica-Alumina Surface

1978 ◽  
Vol 51 (7) ◽  
pp. 1970-1972 ◽  
Author(s):  
Hitofumi Taniguchi ◽  
Tatsuo Masuda ◽  
Kazuo Tsutsumi ◽  
Hiroshi Takahashi
Fuel ◽  
1988 ◽  
Vol 67 (6) ◽  
pp. 803-807 ◽  
Author(s):  
Maria T. Martinez ◽  
Maria D. Martinez ◽  
J. Osácar ◽  
JoséL. Miranda

1986 ◽  
Vol 3 (2) ◽  
pp. 95-108 ◽  
Author(s):  
J. R. González-Velasco ◽  
J. A. González-Marcos ◽  
J. I. Gutiérrez-Ortiz ◽  
A. Romero

Factorial and rotational designs have been used to analyse the effect of each preparative variable on the surface acid strength distribution in silica-alumina catalysts. Relationships between the surface acidities at p Ka = 2·8, 3·3 and 4·8 and the most important variables, namely precipitation rate and temperature, drying pressure and temperature, impregnation concentration and calcination temperature have been obtained.


2017 ◽  
Vol 68 (1) ◽  
pp. 116-120
Author(s):  
Iuliean Vasile Asaftei ◽  
Neculai Catalin Lungu ◽  
Lucian Mihail Birsa ◽  
Ioan Gabriel Sandu ◽  
Laura Gabriela Sarbu ◽  
...  

The conversion of n-heptanes into aromatic hydrocarbons benzene, toluene and xylenes (BTX), by the chromatographic pulse method in the temperature range of 673 - 823K was performed over the HZSM-5 and Ag-HZSM-5 zeolites modified by ion exchange with AgNO3 aqueous solutions. The catalysts, HZSM-5 (SiO2/Al2O3 = 33.9), and Ag-HZSM-5 (Ag1-HZSM-5 wt. % Ag1.02, Ag2-HZSM-5 wt. % Ag 1.62; and Ag3-HZSM-5 wt. % Ag 2.05 having different acid strength distribution exhibit a conversion and a yield of aromatics depending on temperature and metal content. The yield of aromatic hydrocarbons BTX appreciably increased by incorporating silver cations Ag+ into HZSM-5.


2005 ◽  
Vol 84 (1) ◽  
pp. 45-51 ◽  
Author(s):  
Zhihua Wu ◽  
Shenglin Liu ◽  
Sujuan Xie ◽  
Qingxia Wang ◽  
Xinhua Qian ◽  
...  

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