scholarly journals ON THE COMPOSITION OF THE CYANIDE COMPLEX RADICAL OF METALS. PART II. CADMIUM CYANIDE COMPLEX RADICAL

1931 ◽  
Vol 6 (2) ◽  
pp. 60-64 ◽  
Author(s):  
Kosaku Masaki
Keyword(s):  
Cyanide Complex ◽  
Cadmium Cyanide

A New Host Lattice Built of the Werner-Type Copper(I,II) Cyanide Complex Involving a Macrocyclic Ligand

1998 ◽  
Vol 63 (5) ◽  
pp. 622-627 ◽  
Author(s):  
Hidetaka Yuge ◽  
Takayoshi Soma ◽  
Takeshi Ken Miyamoto
Keyword(s):  
Macrocyclic Ligand ◽  
Host Lattice ◽  
Macrocyclic Complex ◽  
Monoclinic Space Group ◽  
Cyanide Complex ◽  
New Host ◽  
Space Group

Crystals of a new clathrate [CuII(hmtd)CuI(CN)3]·CH2Cl2 were afforded from a Me2CO-EtOH-CH2Cl2 solution of a macrocyclic complex CuII(hmtd)CuI(CN)3·2 H2O (hmtd = 5,7,7,12,14,14-hexamethyl- 1,4,8,11-tetraazacyclotetradeca- 4,11-diene). It crystallizes in the monoclinic space group P21/n, a = 7.936(5), b = 18.717(4), c = 17.783(6) Å, β = 98.55(4)°, Z = 4, R = 0.0558 for 1 870 reflections. Unprecedentedly, only one of the three nitrogen-ends of a CuI(CN)3 moiety is coordinated to the square-pyramidal Cu(II) center. The guest CH2Cl2 molecules are captured in the channel between the potlid-shaped [CuII(hmtd)CuI(CN)3] molecules.

scholarly journals Spin-ice physics in cadmium cyanide

2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Chloe S. Coates ◽  
Mia Baise ◽  
Adrian Schmutzler ◽  
Arkadiy Simonov ◽  
Joshua W. Makepeace ◽  
...  
Keyword(s):  
Dipole Moments ◽  
Interaction Strength ◽  
Magnetic Interaction ◽  
Energy Scale ◽  
Spin Ice ◽  
Structural Behaviour ◽  
Geometric Frustration ◽  
Cadmium Cyanide ◽  
The Difference ◽  
Increased Strength

AbstractSpin-ices are frustrated magnets that support a particularly rich variety of emergent physics. Typically, it is the interplay of magnetic dipole interactions, spin anisotropy, and geometric frustration on the pyrochlore lattice that drives spin-ice formation. The relevant physics occurs at temperatures commensurate with the magnetic interaction strength, which for most systems is 1–5 K. Here, we show that non-magnetic cadmium cyanide, Cd(CN)2, exhibits analogous behaviour to magnetic spin-ices, but does so on a temperature scale that is nearly two orders of magnitude greater. The electric dipole moments of cyanide ions in Cd(CN)2 assume the role of magnetic pseudospins, with the difference in energy scale reflecting the increased strength of electric vs magnetic dipolar interactions. As a result, spin-ice physics influences the structural behaviour of Cd(CN)2 even at room temperature.

Biodegradation of Cyanide Complex Compounds in Aqueous Media by Pseudomonas resinovorans

2013 ◽  
Vol 30 (12) ◽  
pp. 757-764 ◽  
Author(s):  
Abdoul-Raimi Bouari ◽  
Shamim Ara Begum ◽  
Ynoussa Maiga ◽  
Nosa O. Egiebor
Keyword(s):  
Aqueous Media ◽  
Complex Compounds ◽  
Cyanide Complex ◽  
Pseudomonas Resinovorans
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