Bifunctional Rhodium Complex Featuring a Silyl–1,8-naphthyridine Si,N-Chelate Ligand: Cooperation of Metal and Pendant Base for Capture and Bond-weakening of BH3

2020 ◽  
Vol 49 (11) ◽  
pp. 1431-1434
Author(s):  
Keita Sato ◽  
Takashi Komuro ◽  
Hisako Hashimoto ◽  
Hiromi Tobita
Keyword(s):  
Rhodium Complex ◽  
Chelate Ligand

Mechanisms of Catalysis in Confined Spaces: Hydrogenation of Norbornadiene with a Rhodium Complex included in a Self-Folding Cavitand

2013 ◽  
Vol 17 (14) ◽  
pp. 1499-1506 ◽  
Author(s):  
Alex Hamilton ◽  
Michael Gicquel ◽  
Pablo Ballester ◽  
Carles Bo
Keyword(s):  
Rhodium Complex ◽  
Confined Spaces

Asymmetric 1,4-Addition of Arylboronic Acids to α,β-Unsaturated Aldehydes Catalyzed by a Chiral Diene–Rhodium Complex

2005 ◽  
Vol 34 (11) ◽  
pp. 1480-1481 ◽  
Author(s):  
Tamio Hayashi ◽  
Norihito Tokunaga ◽  
Kazuhiro Okamoto ◽  
Ryo Shintani
Keyword(s):  
Rhodium Complex ◽  
Arylboronic Acids ◽  
Unsaturated Aldehydes

scholarly journals Metallkomplexe in Anorganischen Matrices, 5 [1] / Metal Complexes in Inorganic Matrices, 5 [1]

1991 ◽  
Vol 46 (6) ◽  
pp. 783-788 ◽  
Author(s):  
Christian Egger ◽  
Ulrich Schubert
Keyword(s):  
Acetic Acid ◽  
Metal Complexes ◽  
Phenylacetic Acid ◽  
Sol Gel ◽  
Rhodium Complex ◽  
Gel Processing ◽  
Inorganic Matrices

A heterogenized rhodium complex, prepared by sol-gel processing of Rh(CO)Cl[PPh2CH2CH2Si(OEt)3]2 and Si(OEt)4, is shown to catalyze the conversion of the silanes H4-nSiPh„ (n = 1 - 3) or (HMe2Si)2O to (poly)siloxanes by air or water. Using THF as a solvent, the silanoles Ph3SiOH or Ph2Si(OH)2 are obtained instead. The reaction of phenylacetic acid or acetic acid with HSiPh3 to give silyl esters is catalyzed by the same compound.

ChemInform Abstract: Ionic Diamine Rhodium Complex Catalyzed Reductive N-Heterocyclization of 2-Nitrovinylarenes.

ChemInform ◽  
2011 ◽  
Vol 42 (37) ◽  
pp. no-no
Author(s):  
Kazumi Okuro ◽  
Joanna Gurnham ◽  
Howard Alper
Keyword(s):  
Rhodium Complex

Synthesis and structural characterisation of neutral pentacoordinate silicon(iv) complexes with a tridentate dianionic N,N,S chelate ligand

2012 ◽  
Vol 41 (7) ◽  
pp. 2148-2162 ◽  
Author(s):  
Claudia Kobelt ◽  
Christian Burschka ◽  
Rüdiger Bertermann ◽  
C. Fonseca Guerra ◽  
F. Matthias Bickelhaupt ◽  
...  
Keyword(s):  
Chelate Ligand ◽  
Structural Characterisation ◽  
Pentacoordinate Silicon
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