scholarly journals Novel Telechelic 2-Methyl-2-Bromopropionate Terminated Polyurethane Macroinitiator for the Synthesis of ABA type Tri-block Copolymers through Atom Transfer Radical Polymerization of Methyl Methacrylate

2008 ◽  
Vol 40 (9) ◽  
pp. 867-874 ◽  
Author(s):  
Hemant Verma ◽  
Tharanikkarasu Kannan
Keyword(s):  
Block Copolymers ◽  
Methyl Methacrylate ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Atom Transfer

scholarly journals Synthesis of Poly(methyl methacrylate)-b-poly(N-isopropylacrylamide) Block Copolymer by Redox Polymerization and Atom Transfer Radical Polymerization

2018 ◽  
Vol 18 (3) ◽  
pp. 537 ◽  
Author(s):  
Melahat Göktaş ◽  
Guodong Deng
Keyword(s):  
Block Copolymers ◽  
Methyl Methacrylate ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Gel Permeation Chromatography ◽  
High Yield ◽  
Resonance Spectroscopy ◽  
Atom Transfer ◽  
Poly Methyl Methacrylate ◽  
Redox Polymerization

Poly(methyl methacrylate)-b-poly(N-isopropylacrylamide) [PMMA-b-PNIPAM] block copolymers were obtained by a combination of redox polymerization and atom transfer radical polymerization (ATRP) methods in two steps. For this purpose, PMMA macroinitator (ATRP-macroinitiator) was synthesized by redox polymerization of methyl methacrylate and 3-bromo-1-propanol using Ce(NH4)2(NO3)6 as a catalyst. The synthesis of PMMA-b-PNIPAM block copolymers was carried out by means of ATRP of ATRP-macroinitiator and NIPAM at 60 °C. The block copolymers were obtained in high yield and high molecular weight. The characterization of products was accomplished by using multi instruments and methods such as nuclear magnetic resonance spectroscopy, Fourier transform infrared spectroscopy, gel permeation chromatography, and thermogravimetric analysis.

Synthesis of methyl methacrylate and N -aryl itaconimide block copolymers via atom-transfer radical polymerization

2005 ◽  
Vol 54 (5) ◽  
pp. 823-828 ◽  
Author(s):  
Vishal Anand ◽  
Seema Agarwal ◽  
Andreas Greiner ◽  
Veena Choudhary
Keyword(s):  
Block Copolymers ◽  
Methyl Methacrylate ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Atom Transfer

Atom Transfer Radical Polymerization of Potassium 3-Sulfopropyl Methacrylate:  Direct Synthesis of Amphiphilic Block Copolymers with Methyl Methacrylate

2004 ◽  
Vol 37 (12) ◽  
pp. 4464-4473 ◽  
Author(s):  
Giancarlo Masci ◽  
Debora Bontempo ◽  
Nicola Tiso ◽  
Marco Diociaiuti ◽  
Luisa Mannina ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Methyl Methacrylate ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Direct Synthesis ◽  
Amphiphilic Block Copolymers ◽  
Atom Transfer

New AB or ABA type block copolymers: atom transfer radical polymerization (ATRP) of methyl methacrylate using iodine-terminated PVDFs as (macro)initiators

2000 ◽  
Vol 44 (1) ◽  
pp. 1-8 ◽  
Author(s):  
Seong-Mu Jo ◽  
Wha-Seop Lee ◽  
Byoung-Sung Ahn ◽  
Kun-You Park ◽  
Kyung-A Kim ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Methyl Methacrylate ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Atom Transfer

Novel poly(methyl methacrylate)-block-polyurethane-block-poly(methyl methacrylate) tri-block copolymers through atom transfer radical polymerization

2008 ◽  
Vol 108 (3) ◽  
pp. 1538-1544 ◽  
Author(s):  
Kannan Tharanikkarasu ◽  
Hemant Verma ◽  
Wonbong Jang ◽  
Seok Kyu Lee ◽  
Jongchul Seo ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Methyl Methacrylate ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Atom Transfer ◽  
Poly Methyl Methacrylate
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