scholarly journals Synthesis and Characterization of Novel Conjugated Polymer with 4H-Cyclopenta[def]phenanthrene and the Sulfanyl Group

2009 ◽  
Vol 41 (2) ◽  
pp. 138-145 ◽  
Author(s):  
Suhee Song ◽  
Youngeup Jin ◽  
Sun Hee Kim ◽  
Joo Hyun Kim ◽  
Kwanghee Lee ◽  
...  
RSC Advances ◽  
2021 ◽  
Vol 11 (21) ◽  
pp. 12995-13003
Author(s):  
Jialin Yang ◽  
Li Yang ◽  
Qianqian Chen ◽  
Keke Guo ◽  
Ji-Min Han

We report a pyridine-flanked diketopyrrolopyrrole monomer and all-acceptor conjugated polymers synthesized therefrom. Photophysical, thermal and electrochemical properties of the polymers have been determined.


2011 ◽  
Author(s):  
M. G. Murali ◽  
D. Udayakumar ◽  
P. Predeep ◽  
Mrinal Thakur ◽  
M. K. Ravi Varma

2018 ◽  
Vol 2018 ◽  
pp. 1-9 ◽  
Author(s):  
Emerson C. G. Campos ◽  
Cristiano Zanlorenzi ◽  
Bruno F. Nowacki ◽  
Gabriela M. Miranda ◽  
Denis A. Turchetti ◽  
...  

This work reports the synthesis and characterization of a conjugated polymer based on fluorene and terpyridine, namely, poly[(9,9-bis(3-((S)-2-methylbutylpropanoate))fluorene-alt-6,6′-(2,2′:6′,2′′-terpyridin-6-yl)] (LaPPS71). The structure was characterized by 1H and 13C nuclear magnetic resonance (NMR) and Fourier-transform infrared (FTIR) spectroscopy. The molar mass was measured by gel permeation chromatography (GPC). As thermal characterization, the glass transition temperature (Tg) was measured by differential scanning calorimetry (DSC). The polymer structure contains two sites capable of complexation with metallic ions, affording the possibility of obtainment of independent or electronically coupled properties, depending on the complexation site. The photophysical properties were fully explored in solution and solid state, presenting ideal results for the preparation of various metallopolymers, in addition to potential application as a metamaterial, due to the presence of the chiral center in the side chains of the polymer.


2011 ◽  
Vol 32 (spc8) ◽  
pp. 3045-3050 ◽  
Author(s):  
Su-Hee Song ◽  
Sung-Heum Park ◽  
Young-Eup Jin ◽  
Il Kim ◽  
Kwang-Hee Lee ◽  
...  

Author(s):  
Bianca Pedroso Silva Santos ◽  
Arthur de Castro Ribeiro ◽  
Jose Geraldo de Melo Furtado ◽  
Maria de Fátima Vieira Marques

Polymeric solar cells (PSCs) are a promising alternative for harnessing solar energy and producing clean and renewable energy. In the present work, a new photovoltaic polymer was synthesized to be applied as an electron donor in PSCs. The conjugated polymer showed high solubility. The optical and electronic properties were investigated in which it was possible to observe wide absorption band and bandgap indicating that it is a promising material for application in solar cells.


2015 ◽  
Vol 3 (9) ◽  
pp. 2024-2032 ◽  
Author(s):  
Jiuchao Dong ◽  
Kohsuke Kawabata ◽  
Hiromasa Goto

A novel chiral inducer was synthesized for obtaining a spirally arranged conjugated polymer without chiral monomers.


1995 ◽  
Vol 413 ◽  
Author(s):  
Qiao-Sheng Hu ◽  
Dilrukshi Vitharana ◽  
Lin Pu

ABSTRACTThe synthesis and characterization of a 1,1′-binaphthyl based main chain chiral conjugated polymer, R-9, is described. The polymer is prepared from the palladium-catalyzed Suzuki coupling of an optically active binaphthyl molecule, (R)-2,2′-dihexyloxy-1,1′-binaphthyl-6,6′- diboronic acid, R-4 with 1,4-bis(p-bromostyryl)benzene (E:Z = 1:1.2), 8. The Suzuki coupling of 8 with 6-neopentyloxynaphthyl-2-boronic acid, 1 1, leads to the formation of a conjugated molecule 10. The structure of this molecule represents the repeat unit of R-9. The electronic absorption spectrum of 10 demonstrates that the degree of conjugation in the chiral conjugated polymer is almost the same as that of its repeat unit.


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