Improvement of Cell Performance and Mechanism of Water Drainage with Surface Hydrophilic Treatment of Gas Diffusion Layer in PEFC

2020 ◽  
Vol 2020 (0) ◽  
pp. 0088
Author(s):  
Satoki Arisawa ◽  
Suguru Uemura ◽  
Yutaka Tabe
Author(s):  
M. Vynnycky ◽  
A. Gordon

An anomaly in the modelling of two-phase flow in the porous cathode gas diffusion layer (GDL) of a polymer electrolyte fuel cell is investigated asymptotically and numerically. Although not commented on previously in literature, the generalized Darcy model used most commonly leads to the surprising prediction that a hydrophilic GDL can lead to better cell performance, in terms of current density, than a hydrophobic one. By analysing a reduced one-dimensional steady-state model and identifying the capillary number as a small dimensionless parameter, we find a potential flaw in the original model, associated with the constitutive relation linking the capillary pressure and the pressures of the wetting and non-wetting phases. Correcting this, we find that, whereas a hydrophilic GDL can sustain a two-phase (gas/liquid) region near the water-producing catalytic layer and gas phase only region further away, a hydrophobic GDL cannot; furthermore, hydrophobic GDLs are found to lead to better cell performance than hydrophilic GDLs, as is indeed experimentally the case.


Author(s):  
Yutaka Tabe ◽  
Daisuke Yoshida ◽  
Kazushige Kikuta ◽  
Takemi Chikahisa ◽  
Masaya Kozakai

This paper investigated the effects of gas and liquid water flow on the performance of a polymer electrolyte membrane (PEM) fuel cell using cells to allow direct observation of the phenomena in the cell and measurements of the local current density and the local pressure loss. The experimental results to compare the separator type indicated the effect of cross-over flow in the gas diffusion layer (GDL) under the lands of serpentine separators on cell performance and the potential of straight channel separator to achieve a relatively-uniform current density distribution. To evaluate the cross-over flow under the land of serpentine separators, a simple circuit model of the gas flow was developed. This analysis showed that slight variations in oxygen concentration caused by the cross-over flow under the land affect the local and overall current density distributions. It was also shown that the establishment of gas paths in the deep layer of GDL by the channels filled with condensed water is effective for stable operation at low flow rates of air in the straight channels.


2014 ◽  
Vol 39 (36) ◽  
pp. 21177-21184 ◽  
Author(s):  
Sheng-Yu Fang ◽  
Lay Gaik Teoh ◽  
Rong-Hsin Huang ◽  
Kan-Lin Hsueh ◽  
Ko-Ho Yang ◽  
...  

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