scholarly journals Kinetics and Mechanism of Oxidation of Phenyl Acetic Acid and Dl-mandelic Acid by Permanganate in Acid Medium

2014 ◽  
Vol 30 (2) ◽  
pp. 681-686 ◽  
Author(s):  
K.Venkata Ratnam ◽  
B.Syama Sundar ◽  
P.S.Radhakrishna murti
Keyword(s):  
Acetic Acid ◽  
Acid Medium ◽  
Mandelic Acid ◽  
Kinetics And Mechanism ◽  
Phenyl Acetic Acid ◽  
Mechanism Of Oxidation

Kinetics and Mechanism of Oxidation of Aliphatic Primary Alcohols with 1-Chlorobenzimidazole in Aqueous Acetic Acid Medium

2016 ◽  
Vol 230 (8) ◽  
Author(s):  
Muthusamy Rukmangathan ◽  
Vetrivel Santhoshkumar ◽  
Balasubramanian Ramkumar
Keyword(s):  
Acetic Acid ◽  
Acid Medium ◽  
Kinetics And Mechanism ◽  
Aqueous Acetic Acid ◽  
Primary Alcohols ◽  
Acetic Acid Medium ◽  
Kinetics Of Oxidation ◽  
First Order ◽  
Mechanism Of Oxidation ◽  
Kinetics Of

AbstractThe kinetics of oxidation of a few aliphatic primary alcohols with 1-chlorobenzimidazole (CBI) was studied in aqueous acetic acid medium. The reactions were found to be first order each with respect to the concentrations of CBI and alcohol. The added HClO

scholarly journals Kinetics and mechanism of oxidation of mandelic acid with Bi(V) in phosphoric acid medium

2020 ◽  
Vol 16 (5) ◽  
pp. 50-57
Author(s):  
MUKESH KUMAR JHA ◽  
◽  
AVINASH KUMAR ◽  
Keyword(s):  
Electron Transfer ◽  
Phosphoric Acid ◽  
Acid Medium ◽  
Mandelic Acid ◽  
Reaction Rate ◽  
Outer Sphere ◽  
Kinetics And Mechanism ◽  
Opposite Charge ◽  
Mechanism Of Oxidation ◽  
Sphere Mechanism

The kinetics and mechanism of oxidation of Mandelic acid with Bi(V) has been investigated in phosphoric acid medium. The order with respect to substrate and oxidant each is one. The reaction rate is independent of [H+] ion as well as [Bi(III)]. The reaction rate decreases with increasing ionic strength indicating reactive species of opposite charge. The simple rate law explained all the experimental observations. The mode of electron transfer from the substrate to Bi(V) has been indicated is a bridged outer sphere mechanism.

Kinetics and Mechanism of Oxidation of Paracetamol by Thallic Perchlorate in Acid Medium

2015 ◽  
Vol 4 (3) ◽  
pp. 302-309 ◽  
Author(s):  
Deepmala Pareek ◽  
Riya Sailani ◽  
Vinita Gupta ◽  
Chandra Khandelwal ◽  
Prem Sharma
Keyword(s):  
Acid Medium ◽  
Kinetics And Mechanism ◽  
Mechanism Of Oxidation
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