Optically observed imbibition and drainage of wetting fluid in nanoporous Vycor glass

2015 ◽  
Vol 32 (12) ◽  
pp. 2397 ◽  
Author(s):  
Shigeo Ogawa ◽  
Jiro Nakamura
Keyword(s):  
1978 ◽  
Vol 39 (C6) ◽  
pp. C6-342-C6-343 ◽  
Author(s):  
E. N. Smith ◽  
D. J. Bishop ◽  
J. E. Berthold ◽  
J. D. Reppy
Keyword(s):  

1974 ◽  
Vol 52 (8) ◽  
pp. 748-752 ◽  
Author(s):  
V. Novotny ◽  
T. M. Holden ◽  
G. Dolling

Neutron diffraction experiments on small particles of lead in the pores of Vycor glass are described. The small particles have a coherence length of (107 ± 20) Å; there is only a slight increase in the lattice parameter as compared with bulk lead, but an analysis of the intensity of the diffraction peaks reveals that there is an increase in the average amplitude of vibration of 28%. At least 80% of the lead in the glass is present in the crystalline state and contributes to the coherent diffraction.


1996 ◽  
Vol 211 (1) ◽  
pp. 173-179 ◽  
Author(s):  
J. A. Duffy ◽  
H. M. Fretwell ◽  
A. P. Clarke ◽  
S. B. Dugdale ◽  
M. A. Alam

Author(s):  
Eslam Ezzatneshan ◽  
Reza Goharimehr

In the present study, a pore-scale multicomponent lattice Boltzmann method (LBM) is employed for the investigation of the immiscible-phase fluid displacement in a homogeneous porous medium. The viscous fingering and the stable displacement regimes of the invading fluid in the medium are quantified which is beneficial for predicting flow patterns in pore-scale structures, where an experimental study is extremely difficult. Herein, the Shan-Chen (S-C) model is incorporated with an appropriate collision model for computing the interparticle interaction between the immiscible fluids and the interfacial dynamics. Firstly, the computational technique is validated by a comparison of the present results obtained for different benchmark flow problems with those reported in the literature. Then, the penetration of an invading fluid into the porous medium is studied at different flow conditions. The effect of the capillary number (Ca), dynamic viscosity ratio (M), and the surface wettability defined by the contact angle (θ) are investigated on the flow regimes and characteristics. The obtained results show that for M<1, the viscous fingering regime appears by driving the invading fluid through the pore structures due to the viscous force and capillary force. However, by increasing the dynamic viscosity ratio and the capillary number, the invading fluid penetrates even in smaller pores and the stable displacement regime occurs. By the increment of the capillary number, the pressure difference between the two sides of the porous medium increases, so that the pressure drop Δp along with the domain at θ=40∘ is more than that of computed for θ=80∘. The present study shows that the value of wetting fluid saturation Sw at θ=40∘ is larger than its value computed with θ=80∘ that is due to the more tendency of the hydrophilic medium to absorb the wetting fluid at θ=40∘. Also, it is found that the magnitude of Sw computed for both the contact angles is decreased by the increment of the viscosity ratio from Log(M)=−1 to 1. The present study demonstrates that the S-C LBM is an efficient and accurate computational method to quantitatively estimate the flow characteristics and interfacial dynamics through the porous medium.


2008 ◽  
Vol 80 (2) ◽  
pp. 263-269
Author(s):  
Iara F. Gimenez ◽  
Oswaldo L. Alves

Thermal behavior of the complexes Pd2(dppm)2Cl2, Pd2(dppm)2(SnCl3)Cl and Pd2(dppm)2(SnCl3)2 (dppm = bis[diphenylphosphino(methane)], ((C6H5)2PCH2P(C6H5)2) in the solid state and immobilized onto porous Vycor glass was studied. Similar decomposition mechanisms were observed for the solid and immobilized complexes, with a small thermal stabilization upon immobilization. The decomposition products were characterized by X-ray diffractometry, Raman and diffuse reflectance infrared spectroscopy, which indicated the presence of a mixture of metallic palladium and oxidized species such as PdO,condensed phosphates, SnO2 and SnP2O7. According to X-ray diffractometry, the decomposition products of the immobilized complexes presented higher amounts of PdO than the solid-state residues, probably as an effect of interactions with silanol groups present in the glass surface.


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