Determination of vapor—liquid equilibrium diagrams of multicomponent systems

2016 ◽  
Vol 70 (12) ◽  
Author(s):  
Leonid Serafimov ◽  
Anastasia Frolkova
Keyword(s):  
Phase Diagram ◽  
Multicomponent Systems ◽  
Liquid Equilibrium ◽  
Vapor Liquid Equilibrium ◽  
Equilibrium Modeling ◽  
Component Systems ◽  
Full Structure ◽  
Concentration Simplex ◽  
Vapor Liquid

AbstractA method for the determination of vapor–liquid phase diagram structure of five-component systems based on the analysis of types and Poincare indexes of singular points of the geometric scan and full structure of the concentration simplex is proposed. Validity of the proposed method was demonstrated by vapor–liquid equilibrium modeling in five-component mixtures: ethanol + water + toluene + butanol + chlorbenzene and acetone + chloroform + ethanol + cyclohexane + water.

scholarly journals Determination of Vapor-Liquid Equilibrium from Total Pressure Measurement

1971 ◽  
Vol 14 (4) ◽  
pp. 252-256 ◽  
Author(s):  
Kunio Nagahama ◽  
Seijiro Suda ◽  
Toshikatsu Hakuta ◽  
Mitsuho Hirata
Keyword(s):  
Pressure Measurement ◽  
Total Pressure ◽  
Liquid Equilibrium ◽  
Vapor Liquid Equilibrium ◽  
Vapor Liquid

Determination of Vapor–Liquid Equilibrium Data in Microfluidic Segmented Flows at Elevated Pressures Using Raman Spectroscopy

2015 ◽  
Vol 87 (16) ◽  
pp. 8165-8172 ◽  
Author(s):  
Sebastian K. Luther ◽  
Simon Stehle ◽  
Kristian Weihs ◽  
Stefan Will ◽  
Andreas Braeuer
Keyword(s):  
Raman Spectroscopy ◽  
Liquid Equilibrium ◽  
Vapor Liquid Equilibrium ◽  
Elevated Pressures ◽  
Equilibrium Data ◽  
Vapor Liquid

VAPOR–LIQUID EQUILIBRIUM MODELING FOR MIXTURES OF HFC-32 + ISOBUTANE AND HFC-32 + HFO-1234ze(E)

2011 ◽  
Vol 19 (02) ◽  
pp. 93-97 ◽  
Author(s):  
RYO AKASAKA
Keyword(s):  
Free Energy ◽  
Helmholtz Free Energy ◽  
Equations Of State ◽  
Dew Point ◽  
Working Fluid ◽  
Liquid Equilibrium ◽  
Vapor Liquid Equilibrium ◽  
Equilibrium Modeling ◽  
Independent Variables ◽  
Vapor Liquid

Vapor–liquid equilibrium (VLE) have been successfully modeled for the binary mixtures of difluoromethane (HFC-32) + isobutane and difluoromethane + trans-1,3,3,3-tetrafluoropropene (HFO-1234ze(E)). These mixtures are considered as possible replacements for conventional refrigerants far from negligible global warming potential (GWP). A multifluid approach explicit in the Helmholtz free energy forms the basis of the model. The independent variables are the temperature, density, and composition. Accurate published equations of state for pure HFC-32, isobutane, and HFO-1234ze(E) are incorporated to calculate the Helmholtz free energy of each component. Typical uncertainties of bubble- and dew-point pressures calculated using the model are within 2%. Although adjustable parameters of the model are determined only from experimental VLE data, it is highly probable that the model reasonably predicts other thermodynamic properties such as enthalpy and heat capacities. Therefore, the model allows practical design and simulation of refrigeration systems using the mixtures as a working fluid.

Sign in / Sign up

Export Citation Format

Share Document