Zn(II)-selective poly (vinyl chloride) (PVC) membrane electrode based on Schiff base ligand 2-benzoylpyridine semicarbazone as an ionophore

2020 ◽  
Vol 40 (10) ◽  
pp. 842-847
Author(s):  
Shankar Suman ◽  
Ram Singh
Keyword(s):  
Schiff Base ◽  
Detection Limit ◽  
Vinyl Chloride ◽  
Pvc Membrane ◽  
Membrane Electrode ◽  
Sodium Tetraphenylborate ◽  
Potential Response ◽  
Selective Electrode ◽  
Poly Vinyl Chloride ◽  
Pvc Membrane Electrode

AbstractA new poly (vinyl chloride) (PVC) membrane electrode using 2-benzoylpyridine semicarbazone as membrane carrier with dioctylphthalate as plasticizer and sodium tetraphenylborate (NaTBP) as anion excluder has been fabricated and investigated as Zn(II)-selective electrode. Best potential response is observed for the composition PVC 30%, plasticizer 58%, NaTBP 8% and ionophore 4% (w/w). The sensor showed a linear stable response over a concentration range of 1.0 × 10−2–4.56 × 10−6 M with a detection limit of 2.28 × 10−6 M and a response time <10 s. The electrode can be used for at least six months without any divergence in potential.

Iodide Selective Electrode Based on Cobalt(II) Complex with Dual-Core Schif Base as Neutral Carrier

2012 ◽  
Vol 549 ◽  
pp. 221-224
Author(s):  
Gang Xu ◽  
Wen Li Dong ◽  
Ling Yan Ren
Keyword(s):  
Schiff Base ◽  
Detection Limit ◽  
Vinyl Chloride ◽  
Wide Concentration Range ◽  
Pvc Membrane ◽  
Selective Electrode ◽  
Neutral Carrier ◽  
Poly Vinyl Chloride ◽  
Dual Core

A new highly selective poly vinyl chloride(PVC) membrane iodide electrode which has neutral carrier of cobalt(Ⅱ) complex with symmetrical binuclear schiff base has been studied. Based on the fact we knew that ethylenediamine could react to acetylacetone and salicylaldehyde. The electrode exhibited near -Nernst response to iodide with a slope of ―54.4 mV/dec over a wide concentration range (1.58×10-7~1.0×10-1 mol/L) with a detection limit of 6.3×10-8 mol/L in phosphorate bufer solution with pH=2.4 at 26°C. After applied to the determination of iodide in pharmaceuticals and salts, the electrode could get satisfied results

Manganese(II)-ion-selective electrode based on 2,2′-bis(salicylideneamino)azobenzene incorporated in poly(vinyl chloride) matrix

2009 ◽  
Vol 74 (9) ◽  
pp. 1411-1424 ◽  
Author(s):  
Mohammad Bagher Gholivand ◽  
Maryam Gorji ◽  
Mohammad Joshaghani
Keyword(s):  
Pvc Membrane ◽  
Indicator Electrode ◽  
Membrane Electrode ◽  
Selective Electrode ◽  
Good Discrimination ◽  
Discrimination Ability ◽  
Poly Vinyl Chloride ◽  
Pvc Membrane Electrode ◽  
Chloride Matrix

A new PVC membrane electrode highly selective to Mn(II), based on 2,2′-bis(salicylideneamino)azobenzene as an ionophore. The electrode exhibits a Nernstian response to Mn(II) ions over a concentration range 0.8 × 10–1–1.1 × 10–7 mol l–1 with a slope of 30.5 ± 0.5 mV per decade and detection limit 5.5 × 10–8 mol l–1. The electrode was used for 45 days at the minimum without any measurable potential divergence. Also, the electrode revealed a fairly good discrimination ability between Mn(II) ions and some cations and anions. The electrode was also utilized as indicator electrode in the potentiometric titration of Mn(II) with EDTA and in determination of Mn(II) in drug as well as tape and river water.

Using of hydrogen ion-selective poly(vinyl chloride) membrane electrode based on calix[4]arene as thiocyanate ion-selective electrode

2006 ◽  
Vol 113 (1) ◽  
pp. 290-296 ◽  
Author(s):  
Sevcan Erden ◽  
Ayça Demirel ◽  
Sahahabuddin Memon ◽  
Mustafa Yılmaz ◽  
Esin Canel ◽  
...  
Keyword(s):  
Vinyl Chloride ◽  
Hydrogen Ion ◽  
Ion Selective Electrode ◽  
Membrane Electrode ◽  
Selective Electrode ◽  
Thiocyanate Ion ◽  
Poly Vinyl Chloride

Thiophene-based Schiff base ligand as ionophore for Ni(II)-selective polyvinyl chloride membrane electrode

2020 ◽  
Vol 40 (6) ◽  
pp. 481-485 ◽  
Author(s):  
Shankar Suman ◽  
Ram Singh
Keyword(s):  
Schiff Base ◽  
Polyvinyl Chloride ◽  
Ethylenediaminetetraacetic Acid ◽  
Pvc Membrane ◽  
Indicator Electrode ◽  
Membrane Electrode ◽  
Nonaqueous Media ◽  
Pvc Membrane Electrode ◽  
Ph Range ◽  
Polyvinyl Chloride Membrane

AbstractA synthesized Schiff base 2-acetylthiophene semicarbazone (3) was used for the preparation of Ni2+ selective polyvinyl chloride (PVC) membrane electrode. The prepared electrode with the optimized composition, PVC:3:sodium tetraphenylborate:di-n-butylphthalate as 33:6:3:58 exhibited a Nernstian response over the working range of 5.0 × 10−6–5.0 × 10−2 mol l−1 with a slope of 29.0 ± 0.3 mV/concentration. The electrode showed good selectivity towards Ni2+ with respect to several metal ions in the pH range of 2.5–10.0 in <15 s with a detection limit of 4.7 × 10−6 mol l−1. The electrode showed the additional benefit of working in partially nonaqueous media having up to 15% (v/v) methanol or ethanol. This electrode was also successfully applied in Ni2+ ion potentiometric titration with ethylenediaminetetraacetic acid as an indicator electrode.

A novel Mn2+ PVC membrane electrode based on a recently synthesized Schiff base

Talanta ◽  
2007 ◽  
Vol 72 (3) ◽  
pp. 1088-1092 ◽  
Author(s):  
Mohammad Hossein Mashhadizadeh ◽  
Ehsan Pour Taheri ◽  
Iran Sheikhshoaie
Keyword(s):  
Schiff Base ◽  
Pvc Membrane ◽  
Membrane Electrode ◽  
Pvc Membrane Electrode

scholarly journals Evaluation of a dioxime-type Schiff base-poly (vinyl chloride) membrane as a silver-ion selective electrode.

2002 ◽  
Vol 51 (9) ◽  
pp. 779-784 ◽  
Author(s):  
Masato UEDA ◽  
Akiyo KOMAI ◽  
Keiichi FUJIMORI ◽  
Takayo MORIUCHI-KAWAKAMI ◽  
Yasuhiko SHIBUTANI
Keyword(s):  
Schiff Base ◽  
Vinyl Chloride ◽  
Silver Ion ◽  
Ion Selective Electrode ◽  
Selective Electrode ◽  
Poly Vinyl Chloride

New Schiff base modified carbon paste and coated wire PVC membrane electrode for silver ion

2006 ◽  
Vol 113 (2) ◽  
pp. 930-936 ◽  
Author(s):  
Mohammad Hossein Mashhadizadeh ◽  
Ali Mostafavi ◽  
Hossein Allah-Abadi ◽  
Iran Sheikhshoai
Keyword(s):  
Schiff Base ◽  
Silver Ion ◽  
Pvc Membrane ◽  
Membrane Electrode ◽  
Carbon Paste ◽  
Pvc Membrane Electrode ◽  
Coated Wire

scholarly journals Fabrication of copper-selective PVC membrane electrode based on newly synthesized copper complex of Schiff base as carrier

2016 ◽  
Vol 20 ◽  
pp. S293-S299 ◽  
Author(s):  
Sulekh Chandra ◽  
Praveen Kumar Tomar ◽  
Avdhesh Kumar ◽  
Amrita Malik ◽  
Arendra Singh
Keyword(s):  
Schiff Base ◽  
Copper Complex ◽  
Pvc Membrane ◽  
Membrane Electrode ◽  
Pvc Membrane Electrode
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