Recent advances in the chemistry of uranium halides in anhydrous ammonia

2018 ◽  
Vol 233 (12) ◽  
pp. 817-844 ◽  
Author(s):  
Stefan S. Rudel ◽  
Sebastian A. Baer ◽  
Patrick Woidy ◽  
Thomas G. Müller ◽  
H.-Lars Deubner ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Liquid Ammonia ◽  
Ammine Complexes ◽  
Anhydrous Ammonia ◽  
Hydrolysis Products ◽  
Recent Advances

Abstract This article presents an overview of recent advancements in the field of uranium chemistry, paying special attention to the preparation of starting materials and to the chemistry of uranium halides in liquid ammonia. Where suitable, insights into the chemistry of thorium are also presented. Herein, we report upon the crystal structures of several ammine complexes as well as their deprotonation products. Specific examples of hydrolysis products in liquid ammonia are showcased. Additionally, advancements in the preparation of uranium cyanides are presented.

Preparation and crystal structures of the beryllium ammines [Be(NH3)4]X2 (X = Br, I, CN, SCN, N3) and Be(NH3)2X'2 (X' = Cl, Br, I)

2019 ◽  
Vol 55 (91) ◽  
pp. 13649-13652 ◽  
Author(s):  
Matthias Müller ◽  
Magnus R. Buchner
Keyword(s):  
Solid State ◽  
Crystal Structures ◽  
Liquid Ammonia ◽  
Ammonium Salts ◽  
Ammine Complexes ◽  
Pseudo Halides

Ammine complexes of beryllium halides and pseudo-halides have been synthesized through the reaction of metallic beryllium with ammonium salts in liquid ammonia or in the solid state.

Recent Advances in the Opportunities for Solving Molecular Crystal Structures Directly from Powder Diffraction Data

2002 ◽  
Vol 389 (1) ◽  
pp. 123-129 ◽  
Author(s):  
Kenneth D. M. Harris ◽  
Roy L. Johnston ◽  
Giles W. Turner ◽  
Emilio Tedesco ◽  
Eugene Y. Cheung ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Powder Diffraction ◽  
Diffraction Data ◽  
Molecular Crystal ◽  
Powder Diffraction Data ◽  
Recent Advances
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