ChemInform Abstract: Reactions of Beryllium Halides in Liquid Ammonia: The Tetraammineberyllium Cation [Be(NH3)4]2+, Its Hydrolysis Products, and the Action of Be2+as a Fluoride-Ion Acceptor.

ChemInform ◽  
2012 ◽  
Vol 43 (19) ◽  
pp. no-no
Author(s):  
Florian Kraus ◽  
Sebastian A. Baer ◽  
Magnus R. Buchner ◽  
Antti J. Karttunen
1972 ◽  
Vol 25 (2) ◽  
pp. 407 ◽  
Author(s):  
GW O'Donnell ◽  
GN Richards

1',6,6'-Tri-O-methylsucrose, a new compound, has been synthesized by methylation of 2,3,3',4,4'-penta-O-acetylsucrose with diazomethane and boron trifluoride with subsequent deacetylation. 2,3,3',4,4'-Penta-O-methylsucrose has been obtained in improved yield from the tri-O-trityl derivative by reduction with lithium in liquid ammonia. A major product of the incomplete methylation of 11,6,6'-tri-O-tritylsucrose was the 2,3,3',4'-tetra-O-methyl derivative, and after reductive detritylation 2,3,3',4'-tetra-O-methylsucrose, a new compound, was isolated and identified by examination of its hydrolysis products.


2018 ◽  
Vol 233 (12) ◽  
pp. 817-844 ◽  
Author(s):  
Stefan S. Rudel ◽  
Sebastian A. Baer ◽  
Patrick Woidy ◽  
Thomas G. Müller ◽  
H.-Lars Deubner ◽  
...  

Abstract This article presents an overview of recent advancements in the field of uranium chemistry, paying special attention to the preparation of starting materials and to the chemistry of uranium halides in liquid ammonia. Where suitable, insights into the chemistry of thorium are also presented. Herein, we report upon the crystal structures of several ammine complexes as well as their deprotonation products. Specific examples of hydrolysis products in liquid ammonia are showcased. Additionally, advancements in the preparation of uranium cyanides are presented.


1976 ◽  
Vol 73 ◽  
pp. 849-851 ◽  
Author(s):  
Thomas Kottarathil ◽  
Gérard Lepoutre

2010 ◽  
Vol 6 (3) ◽  
pp. 174-183 ◽  
Author(s):  
Maria Saavedra ◽  
Anabela Borges ◽  
Carla Dias ◽  
Alfredo Aires ◽  
Richard Bennett ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document