Arrhenius-Parameter und kinetischer Isotopeneffekt für die Reaktion von Wasserstoffatomen mit Silan
1974 ◽
Vol 29
(3)
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pp. 493-496
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The Reaction of Hydrogen Atoms with Silane; Arrhenius Parameters and Kinetic Isotope Effect Relative rate constants were measured for the systems H + C2H4/SiD4 and D + C2D4/SiH4 over a wide temperature range. From the known arrheniusparameter for the reaction H + C2H4 the activation energy EA and the preexponential factor A of the abstraction reactionH + SiD4 → HD + SiD3may be calculated. Values of EA = 3.2 kcal/Mol and A = 4.92 • 1013 cm3 Mol-1 sec-1 were obtained. Upper limits for the kinetic isotope effects are given in the paper
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2015 ◽
Vol 93
(4)
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pp. 463-467
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2001 ◽
Vol 107
(1)
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pp. 15-21
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2003 ◽
Vol 118
(14)
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pp. 6280-6288
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2016 ◽
Vol 18
(15)
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pp. 10144-10151
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