Kinetic isotope effects for fast deuterium and proton exchange rates
2016 ◽
Vol 18
(15)
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pp. 10144-10151
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Keyword(s):
By monitoring the effect of deuterium decoupling on the decay of transverse 15N magnetization in D–15N spin pairs during multiple-refocusing echo sequences, we have determined fast D–D exchange rates kD and compared them with fast H–H exchange rates kH in tryptophan to determine the kinetic isotope effect as a function of pH and temperature.
Keyword(s):
1992 ◽
Vol 114
(4)
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pp. 1502-1503
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1975 ◽
Vol 71
(0)
◽
pp. 1937
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1974 ◽
Vol 96
(12)
◽
pp. 3721-3727
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Keyword(s):