Electronic Overlap Population as Reactivity Measure IV. Bond Cleavage and Bond Formation Processes
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Abstract Electronic overlap population is explored as a reactivity measure for several bond cleavage and bond formation processes. The reactions considered include: I. decarboxylation of carboxylic acids and of their anions; II. carbon-hydrogen bond cleavage in γ-radiolysis of glutaric, methyl-malonic and 3-hexendioic acids; and, III. hydrogen atom addition to butadiene and to sorbic acid.
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1991 ◽
Vol 12
(1)
◽
pp. 1-33
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1997 ◽
Vol 63
(6)
◽
pp. 1099-1106
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