Vibronic Ground State Rotational Spectrum of 3-Bromothiophene
1983 ◽
Vol 38
(11)
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pp. 1238-1247
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Keyword(s):
Set Up
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The rotational spectrum of 3-bromothiophene was investigated in the frequency range between 8 and 18 GHz by use of a microwave Fourier transform spectrometer. Both a- and b-type spectra were assigned for the vibronic ground state. Rotational constants, quartic centrifugal distortion constants and quadrupole coupling constants were obtained for the 79Br- and 81Br-isotopic species. For the analysis, the effective rotational Hamiltonian including centrifugal distortion in the form of Van Eijck's symmetric top reduction and bromine quadrupole coupling was set up in the coupled basis of the limiting symmetric top, J, K, I, F, MF>, and was diagonalized numerically. Spin rotation interaction was neglected
1993 ◽
Vol 48
(3)
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pp. 514-518
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1996 ◽
Vol 51
(1-2)
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pp. 123-128
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1993 ◽
Vol 48
(12)
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pp. 1219-1222
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1991 ◽
Vol 46
(9)
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pp. 770-776
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1986 ◽
Vol 41
(7)
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pp. 955-958
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