35Cl NQR Spectroscopy on Salts and Molecular Compounds of Trichloroacetic Acid

1986 ◽  
Vol 41 (1-2) ◽  
pp. 215-224 ◽  
Author(s):  
Winfried Fichtner ◽  
Axel Markworth ◽  
Norbert Weiden ◽  
Alarich Weiss

The temperature dependence of salts M(1)H(Cl3CCOO)2 and molecular compounds of trichloroacetic acid with amines and benzaldehydes, TCA · X, was studied,The data fit rather well to the known dependence of the mean frequency shift Δ <v(35Cl)> on the pkadifference of X with respect to TCA. A linear relation is observed between the bleaching out temperature Tb of the 35Cl NQR lines and Δ <v(35Cl)> for M(1)H(Cl3CCOO)2 and for TCA · X, X = benzaldehydes.

1993 ◽  
Vol 58 (2) ◽  
pp. 234-243 ◽  
Author(s):  
Viliam Klimo ◽  
Martina Bittererová ◽  
Stanislav Biskupič ◽  
Ján Urban ◽  
Miroslav Micov

The reaction O + OH → O2 + H in conditions of combustion of hydrocarbons and polymers was modelled by using the method of quasiclassical trajectories. The potential energy surface was determined by the multiconfiguration interaction method and fitted with the analytical form of the extended LEPS function. Attention was paid to the mean values of the vibrational and rotational quantum numbers of O2 molecules and their temperature dependence. The temperature dependence of the mean lifetime of the OOH collision complex was also examined. The calculated rate constants were analyzed and compared with the experimental data over the temperature region of the combustion processes.


Author(s):  
Vittorio Basso ◽  
Alessandro Sola ◽  
Patrizio Ansalone ◽  
Michaela Kuepferling

2021 ◽  
pp. bmjqs-2021-013015
Author(s):  
Vineet Chopra ◽  
Megan O'Malley ◽  
Jennifer Horowitz ◽  
Qisu Zhang ◽  
Elizabeth McLaughlin ◽  
...  

BackgroundThe Michigan Appropriateness Guide for Intravenous Catheters (MAGIC) provides evidence-based criteria for peripherally inserted central catheter (PICC) use. Whether implementing MAGIC improves PICC appropriateness and reduces complications is unknown.MethodsA quasiexperimental study design to implement MAGIC in 52 Michigan hospitals was used. Data were collected from medical records by trained abstractors. Hospital performance on three appropriateness criteria was measured: short-term PICC use (≤5 days), use of multilumen PICCs and PICC placement in patients with chronic kidney disease. PICC appropriateness and device complications preintervention (January 2013 to December 2016) versus postintervention (January 2017 to January 2020) were compared. Change-point analysis was used to evaluate the effect of the intervention on device appropriateness. Logistic regression and Poisson models were fit to assess the association between appropriateness and complications (composite of catheter occlusion, venous thromboembolism (VTE) and central line-associated bloodstream infection (CLABSI)).ResultsAmong 38 592 PICCs, median catheter dwell ranged from 8 to 56 days. During the preintervention period, the mean frequency of appropriate PICC use was 31.9% and the mean frequency of complications was 14.7%. Following the intervention, PICC appropriateness increased to 49.0% (absolute difference 17.1%, p<0.001) while complications decreased to 10.7% (absolute difference 4.0%, p=0.001). Compared with patients with inappropriate PICC placement, appropriate PICC use was associated with a significantly lower odds of complications (OR 0.29, 95% CI 0.25 to 0.34), including decreases in occlusion (OR 0.25, 95% CI 0.21 to 0.29), CLABSI (OR 0.61, 95% CI 0.46 to 0.81) and VTE (OR 0.40, 95% CI 0.33 to 0.47, all p<0.01). Patients with appropriate PICC placement had lower rate of complications than those with inappropriate PICC use (incidence rate ratio 0.987, 95% CI 0.98 to 0.99, p<0.001).ConclusionsImplementation of MAGIC in Michigan hospitals was associated with improved PICC appropriateness and fewer complications. These findings have important quality, safety and policy implications for hospitals, patients and payors.


2018 ◽  
Vol 16 (8) ◽  
pp. 2108-2114 ◽  
Author(s):  
Andres Rojas ◽  
Angel Farfan ◽  
Esteban Mora ◽  
Luis I. Minchala ◽  
Sara Wong

1982 ◽  
Vol 62 (1) ◽  
pp. 183-188 ◽  
Author(s):  
R. RIOUX

Barley (Hordeum vulgare L. ’Champlain’) was grown with quackgrass (Agropyron repens (L.) Beauv.) at various densities for 3 yr. According to the regression analysis, a linear relation is appropriate to describe the relationship between yield of barley and biomass or density of quackgrass. A greater proportion of yield variability was explained by density (64%) than by biomass (40%). Density is then a better criterion than biomass to predict yield lost in barley. The linear relationship between barley yield and the shoot density of quackgrass is estimated by the following equation: yield barley = 345.3–0.5682 dens, quackgrass. An increase of 10 shoots/m2 in the mean density of quackgrass resulted in a mean loss of 6 g/m2 in the yield of barley.


Sign in / Sign up

Export Citation Format

Share Document