Helium Atom Scattering from Cyclopentane, Pyrrolidine and Tetrahydrofurane in Crossed Molecular Beams

1997 ◽  
Vol 52 (5) ◽  
pp. 425-431
Author(s):  
Christian Gebauer ◽  
Olaf Klein ◽  
Ralf Schmidt ◽  
Wolfhart Seidel

Abstract Scattering of helium atoms by cyclopentane, pyrrolidine and tetrahydrofurane molecules was ob-served in crossed molecular beam experiments. The intensity of scattered helium atoms, depending on the scattering angle, was measured with high resolution, and the damping of the diffraction oscillations of the differential cross sections was used to extract elastic anisotropic interaction potentials for these molecules. The evaluation included a geometric transformation concerning the puckered states of the envelope and the twisted conformation of the molecules. The potentials were found to be rather similar.

1995 ◽  
Vol 50 (4-5) ◽  
pp. 468-474 ◽  
Author(s):  
Christian Gebauer ◽  
Olaf Klein ◽  
Ralf Schmidt ◽  
Wolfhart Seidel

Abstract Differential cross sections have been measured by scattering He atoms from CFnCl4-n (1≤n≤4) in crossed molecular beams. The damping of the diffraction oscillations was used to extract interaction potentials for these molecules which range from nearly isotropic to rather anisotropic. Macroscopic binary parameters, as second virial coefficients, diffusion coefficients and viscosities were calculated from these potentials


1997 ◽  
Vol 52 (10) ◽  
pp. 695-701
Author(s):  
Markus Hammer ◽  
Wolfhart Seidel

Abstract Rotationally unresolved differential cross sections were measured in crossed molecular beam experiments by scattering Helium atoms from Ethane, 1,1-Difluoroethane, 1,1,1,2-Tetrafluoroethane and Hexafluoroethane. The damping of observed diffraction oscillations was used to extract anisotropic interaction potentials for these scattering systems applying the infinite order sudden approximation (IOSA). Binary macroscopic parameters such as second heterogeneous virial coefficients and the coefficients of diffusion and viscosity were computed from these potentials and compared to results from macroscopic experiments.


1996 ◽  
Vol 357-358 ◽  
pp. 639-644 ◽  
Author(s):  
Jeff Baker ◽  
J.J. Hernández ◽  
Jaime Li ◽  
J.G. Skofronick ◽  
S.A. Safron ◽  
...  

1998 ◽  
Vol 108 (18) ◽  
pp. 7825-7834 ◽  
Author(s):  
Andrew P. Graham ◽  
Frank Hofmann ◽  
J. Peter Toennies ◽  
Gwyn P. Williams ◽  
Carol J. Hirschmugl ◽  
...  

Author(s):  
David H. Van Winkle ◽  
J. G. Skofronick ◽  
T. W. Trelenberg ◽  
S. A. Safron ◽  
F. A. Flaherty

The specular diffraction intensity of helium atoms from KTa0.48Nb0.52O3 surfaces undergoes dramatic fluctuations as a function of surface temperature.


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