Photolysis (A = 185 nm) of Liquid Acetaldehyde Dimethyl Acetal
1977 ◽
Vol 32
(2)
◽
pp. 205-208
◽
Keyword(s):
Deaerated liquid acetaldehyde dimethyl acetal has been photolyzed at λ = 185 nm, and 28 products have been determined. The major ones with their quantum yields are: methanol (0.59), methane (0.26), ethyl methyl ether (0.17), methyl vinyl ether (0.16), methyl formate (0.14), ketene dimethyl acetal (0.1), ethane (0.06), hydrogen (0.06), and acetaldehyde (0.06).The major primary processes are suggested to be the scission of the C-OCH3 bonds (homolytic and molecular) and of the O-CH3 bonds (homolytic). Minor processes are hydrogen elimination reactions and the scission of the C-CH3 bond.
1977 ◽
Vol 36
(1)
◽
pp. 133-147
◽
1969 ◽
Vol 91
(10)
◽
pp. 2487-2492
◽
Keyword(s):
2002 ◽
Vol 23
(4)
◽
pp. 282-285
◽
Keyword(s):
1999 ◽
Vol 193
(1)
◽
pp. 150-158
◽
Keyword(s):
2003 ◽
Vol 204
(17)
◽
pp. 2090-2098
◽
Keyword(s):