Notizen: Darstellung und Kristallstruktur von α- und β-Cu3TiO4 / Preparation and Crystal Structure of α- and β-Cu3TiO4

1977 ◽  
Vol 32 (11) ◽  
pp. 1356-1357 ◽  
Author(s):  
Klaus-Jürgen Range ◽  
Fritz Ketterl
Keyword(s):  
Crystal Structure ◽  
Ternary System ◽  
Crystal Structures ◽  
Octahedral Coordination ◽  
Distorted Octahedral Coordination ◽  
Distorted Octahedral

A compound Cu3TiO4 was found to exist in the ternary system CuO-Cu2O-TiO2. The crystal structures of two modifications are very similar and contain Cu+ with linear, Cu2+ and Ti4+ with trigonal distorted octahedral coordination.

Notizen: Über die Kristallstruktur von β-SCl3+SbCl6- und interionischen Wechselwirkungen in SCl3+-Salzen/The Crystal Structure of β-SCl3+SbCl6- and Interionic Interactions in SCl3+ Salts

1992 ◽  
Vol 47 (4) ◽  
pp. 594-596 ◽  
Author(s):  
Rolf Minkwitz ◽  
Andreas Kornath ◽  
Hans Preut
Keyword(s):  
Crystal Structure ◽  
Crystal Structures ◽  
Unit Cell ◽  
Octahedral Coordination ◽  
Monoclinic Space Group ◽  
Space Group ◽  
Distorted Octahedral Coordination ◽  
Distorted Octahedral ◽  
Interionic Interactions

Chlorosulfonium hexachloroantimonate crystallizes in the monoclinic space group C 2/m with a = 1405.5(3) pm, b = 1055.1(2) pm , c = 882.2(2) pm, β = 110.05(3)° at 169 K with 4 formula units per unit cell. A distorted octahedral coordination around sulphur is formed by three S - C l bonds and three interionic sulphur chlorine contacts. The interionic interactions in SCl3+ salts of known crystal structures are discussed.

scholarly journals Crystal structures offac-trichloridotris(trimethylphosphane-κP)rhodium(III) monohydrate andfac-trichloridotris(trimethylphosphane-κP)rhodium(III) methanol hemisolvate: rhodium structures that are isotypic with their iridium analogs

2015 ◽  
Vol 71 (2) ◽  
pp. 226-230 ◽  
Author(s):  
Joseph S. Merola ◽  
Marion A. Franks
Keyword(s):  
Crystal Lattice ◽  
Crystal Structures ◽  
Octahedral Coordination ◽  
Distorted Octahedral Coordination ◽  
Distorted Octahedral ◽  
Coordination Spheres

The crystal structures of two solvates offac-trichloridotris(trimethylphosphane-κP)rhodium(III) are reported,i.e.one with water in the crystal lattice,fac-[RhCl3(Me3P)3]·H2O, and one with methanol in the crystal lattice,fac-[RhCl3(Me3P)3]·0.5CH3OH. These rhodium compounds exhibit distorted octahedral coordination spheres at the metal and are isotypic with the analogous iridium compounds previously reported by us [Merolaet al.(2013).Polyhedron,54, 67–73]. Comparison is made between the rhodium and iridium compounds, highlighting their isostructural relationships.

scholarly journals Crystal structure of chlorido(dimethyl sulfoxide-κS)bis[4-(pyridin-2-yl)benzaldehyde-κ3C2,N]iridium(III) acetonitrile monosolvate

2017 ◽  
Vol 73 (9) ◽  
pp. 1279-1281 ◽  
Author(s):  
Andrew J. Peloquin ◽  
Madelyn B. Smith ◽  
Gary J. Balaich ◽  
Scott T. Iacono
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Dimethyl Sulfoxide ◽  
Coordination Sphere ◽  
Title Compound ◽  
Octahedral Coordination ◽  
Distorted Octahedral Coordination ◽  
Hydrogen Bonding Interactions ◽  
Distorted Octahedral ◽  
Chloride Ligand

The title compound, [IrCl(C12H8NO)2{(CH3)2SO}]·H3CCN or [IrCl(fppy)2(DMSO)]·H3CCN [where fppy is 4-(pyridin-2-yl)benzaldehyde and DMSO is dimethyl sulfoxide], is a mononuclear iridium(III) complex including two fppy ligands, a sulfur-coordinating DMSO ligand, and one terminal chloride ligand that define a distorted octahedral coordination sphere. The complex crystallizes from 1:1 DMSO–acetonitrile as an acetonitrile solvate. In the crystal, weak C—H...O and C—H...N hydrogen-bonding interactions between adjacent complexes and between the acetonitrile solvent and the complex consolidate the packing.

scholarly journals Crystal structure of poly[μ-acetato-bis[μ-2-oxo-2-(quinolin-8-yl)ethanoato]trisodium]

2014 ◽  
Vol 70 (11) ◽  
pp. m385-m386
Author(s):  
Rachel L. Nicholls ◽  
Christopher M. Pask ◽  
Bao Nguyen
Keyword(s):  
Crystal Structure ◽  
Diethyl Ether ◽  
Title Compound ◽  
Octahedral Coordination ◽  
Coordination Geometry ◽  
Axis Direction ◽  
Distorted Octahedral Coordination ◽  
Distorted Octahedral Coordination Geometry ◽  
Distorted Octahedral ◽  
Through Diffusion

The title compound [Na3(C11H6NO3)2(C2H3O2)]n, crystallized through diffusion of diethyl ether into methanol as needles. There are three crystallographically independent Na+cations present, each exhibiting a distorted octahedral coordination geometry, two through coordination by five O atoms and one N atom, and one through coordination by six O atoms. A series of intermolecular O...Na and N...Na contacts leads to the formation of chains along thea-axis direction.

Oxotitan-Addukte mit Dimethylsulfoxid: [TiO(OSMe2)5]Cl2 und [Ti4O6(OSMe2)12]Cl4 · 5Me2SO · 1/2 H2O / Oxotitanium Compounds with Dimethylsulfoxide: [TiO(OSMe2)5]Cl2 and [Ti4O6(OSMe2)12]Cl4 · 5Me2SO · 1/2 H2O

1997 ◽  
Vol 52 (11) ◽  
pp. 1291-1295 ◽  
Author(s):  
Susanne Rabe ◽  
Ulrich Müller
Keyword(s):  
Crystal Structure ◽  
Structure Determination ◽  
Titanium Atom ◽  
Crystal Structure Determination ◽  
Octahedral Coordination ◽  
Crystal Data ◽  
Distorted Octahedral Coordination ◽  
Distorted Octahedral

While TiCl4 and Na2S4 react in in the presence of PPh4Cl in dichloromethane to yield (PPh4)2[TiSCl4]·2CH2Cl2, we obtained [Ti4O6(OSMe2)12]Cl4·5Me2SO · 1/2H2O (1) from the same reactants in dimethylsulfoxide. Compound 1 is only stable in the presence of dimethylsulfoxide. The crystal structure determination at 153 K shows the presence of cations having an adamantane-like Ti4O64+ skeleton with three Me2SO molecules coordinated to each Ti atom via their O atoms. Crystal data: monoclinic, P 21/n, Z = 4, a = 1096.9, b = 3097, c = 2342.7 pm, β = 93.90° (at -120 °C; R = 0.087 % for 4098 reflections). In an attempt to produce the same compound only from TiCl4 and Me2SO, [TiO(OSMe2)5]Cl2 was obtained. Its cation has a rather short Ti=O bond (164.8 pm) and a distorted octahedral coordination of the titanium atom. The crystals are triclinic, P1̄, Z = 2, R = 0.050 for 2063 reflections measured at 153 K.

scholarly journals Crystal structure of hexakis(μ2-4-tert-butoxy-4-oxobut-2-en-2-olato)trizinc

2014 ◽  
Vol 70 (12) ◽  
pp. 483-485
Author(s):  
Olgerd O. Shtokvish ◽  
Lyudmila I. Koval ◽  
Vasyl I. Pekhnyo
Keyword(s):  
Crystal Structure ◽  
Metal Cations ◽  
Title Complex ◽  
Octahedral Coordination ◽  
Coordination Geometry ◽  
Linear Fashion ◽  
Distorted Octahedral Coordination ◽  
Distorted Octahedral Coordination Geometry ◽  
Distorted Octahedral

The title complex, systematic name hexakis(μ2-4-tert-butoxy-4-oxobut-2-en-2-olato)-1:2κ9O2,O4:O2;2:3κ9O2,O4:O2-trizinc, [Zn3(C8H13O3)6], synthesized fromtert-butyl acetoacetate and diethylzinc, consists of trinuclear centrosymmetric molecules of an approximateC3isymmetry. The three metal cations are arranged in a linear fashion, with the central ZnIIatom located on a centre of symmetry. All three metal cations exhibit a distorted octahedral coordination geometry. The terminal ZnIIcations are chelated by threetert-butyl acetoacetate ligands and these units are connected to the central ZnIIatom by the bridging enolate O atoms.

scholarly journals Crystal structure ofcatena-poly[[bis(acetato-κO)copper(II)]-bis[μ-4-(1H-imidazol-1-yl)phenol]-κ2N3:O;κ2O:N3]

2017 ◽  
Vol 73 (2) ◽  
pp. 209-212
Author(s):  
Mehmet Poyraz ◽  
Musa Sarı
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Title Compound ◽  
Octahedral Coordination ◽  
Stacking Interactions ◽  
Coordination Environment ◽  
Heterocyclic Ligand ◽  
Distorted Octahedral Coordination ◽  
Distorted Octahedral ◽  
Distorted Octahedral Coordination Environment

In the title compound, [Cu(CH3COO)2(C9H8N2O)2]n, the CuIIion resides on a centre of inversion, displaying a tetragonally distorted octahedral coordination environment defined by two pairs of N and O atoms of symmetry-related 4-(1H-imidazol-1-yl)phenol ligands and the O atoms of two symmetry-related acetate ligands. The bridging mode of the 4-(1H-imidazol-1-yl)phenol ligands is associated with a very long Cu...O interactions involving the phenol O atom of the heterocyclic ligand, which creates chains extending parallel to [100]. In the crystal, the chains are arranged in a distorted hexagonal rod packing and are linkedviaC—H...O hydrogen bonds and by π–π stacking interactions involving centrosymmetrically related pairs of imidazole and phenol rings.

scholarly journals Synthesis and crystal structure of bis(1H-benzo[d][1,2,3]triazole-κN2){2,2′-[N-(phenylphosphorylmethyl-κO)azanediyl]diacetato-κ3O,N,O′}cobalt(II)–1H-benzo[d][1,2,3]triazole (1/1)

2017 ◽  
Vol 73 (11) ◽  
pp. 1704-1707
Author(s):  
Chao-Jun Du ◽  
Xiao-Na Zhao
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Title Compound ◽  
Three Dimensional ◽  
Octahedral Coordination ◽  
Supramolecular Architecture ◽  
Synthesis And Crystal Structure ◽  
Distorted Octahedral Coordination ◽  
Distorted Octahedral ◽  
Benzene Rings

In the title compound, [Co(C11H12NO6P)(C6H5N3)2]·C6H5N3, the 2,2′-[N-(phenylphosphorylmethyl-κO)azanediyl]diacetate dianionN,O,O′,O′′-chelates the CoIIcation and two 1H-benzo[d][1,2,3]triazole molecules coordinate to the CoIIcation to complete the slightly distorted octahedral coordination. In the crystal, classical O—H...O, N—H...O hydrogen bonds and weak C—H...N hydrogen bonds link the molecules into a three-dimensional supramolecular architecture. π–π stacking between the triazole and benzene rings and between the benzene rings is also observed in the crystal.

scholarly journals Crystal structures of (μ2-η2,η2-4-hydroxybut-2-yn-1-yl 2-bromo-2-methylpropanoate-κ4C2,C3:C2,C3)bis[tricarbonylcobalt(II)](Co—Co) and [μ2-η2,η2-but-2-yne-1,4-diyl bis(2-bromo-2-methylpropanoate)-κ4C2,C3:C2,C3]bis[tricarbonylcobalt(II)](Co—Co)

2014 ◽  
Vol 70 (7) ◽  
pp. 9-13
Author(s):  
C. John McAdam ◽  
Stephen C. Moratti ◽  
Brian H. Robinson ◽  
Jim Simpson ◽  
Roderick G. Stanley
Keyword(s):  
Crystal Structure ◽  
Crystal Structures ◽  
Coordination Geometry ◽  
Carbonyl Ligands ◽  
Axis Direction ◽  
Distorted Octahedral Coordination ◽  
Dicobalt Octacarbonyl ◽  
Distorted Octahedral Coordination Geometry ◽  
Distorted Octahedral ◽  
Cluster Cores

The title compounds, [Co2(C8H11BrO3)(CO)6], (1), and [Co2(C12H16Br2O4)(CO)6], (2), result from the replacement of two carbonyl ligands from dicobalt octacarbonyl by the alkynes 4-hydroxybut-2-ynyl 2-bromo-2-methylpropanoate and but-2-yne-1,4-diyl bis(2-bromo-2-methylpropanoate), respectively. Both molecules have classic tetrahedral C2Co2cluster cores with the CoIIatoms in a highly distorted octahedral coordination geometry. The alkyne ligands both adopt acis-bent conformation on coordination. In the crystal structure of (1), classical O—H...O and non-classical C—H...O contacts form inversion dimers. These combine with weak O...O and Br...O contacts to stack the molecules into interconnected columns along theb-axis direction. C—H...O and C—H...Br contacts stabilize the packing for (2), and a weak Br...O contact is also observed. Interconnected columns of molecules again form along theb-axis direction.

[Tris(2-aminoethyl)amine-κ3 N,N′,N′′,N′′′](L-tyrosinato-κ2 N,O)nickel(II) iodide dihydrate

2006 ◽  
Vol 62 (7) ◽  
pp. m1668-m1670 ◽  
Author(s):  
Yamei Pei ◽  
Li Wang
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Title Compound ◽  
Three Dimensional ◽  
Octahedral Coordination ◽  
Coordination Environment ◽  
Distorted Octahedral Coordination ◽  
Dimensional Network ◽  
Distorted Octahedral ◽  
Distorted Octahedral Coordination Environment

In the title compound, [Ni(C9H10NO3)(C6H18N4)]I·2H2O, the NiII atom is in a slightly distorted octahedral coordination environment. In the crystal structure, extensive hydrogen bonding links molecules into a three-dimensional network.

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