N2H4-Koordination an Eisen-Schwefel-Zentren: Synthese und Struktur von [N(C4H9)4]2[μ-N2H4{Fe(S2C6H4)2}2]/N2H4Coordination on Iron Sulfur Centres: Synthesis and Structure of [N(C4H9)4]2[μ-N2H4{Fe(S2C6H4)2}2]
1978 ◽
Vol 33
(11)
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pp. 1341-1346
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Abstract The reactions of N2H4 and N2H4 · H2O respectively, with [N(C4H9)4][Fe(S2C6H4)2] are investigated. With N2H4 · H2O the complex salt [N(C4H9)4]2[μ-N2H4{Fe(S2C6H4)2}2] is obtained, the first hydrazine complex of a dithiolato transition metal system, which can be fully characterized. The structure shows, that the compound consists of discrete cations and anions; in the centrosymmetrical anions two [FeS4] centres are bridged by a hydrazine ligand with Fe-N distances of 224 pm, N-N distances of 142 pm and Fe-N-N angles of 116.1°. The iron atoms are square pyramidally configurated and located 35 pm above the plane determined by the S atoms.
1971 ◽
Vol 32
(C1)
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pp. C1-221-C1-223
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2008 ◽
Vol 460
(1-2)
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pp. 708-713
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2007 ◽
Vol 539-543
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pp. 1937-1942
1987 ◽
Vol 91
(17)
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pp. 4433-4435
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2012 ◽
Vol 113
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pp. 427-437
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1985 ◽
Vol 75
(1-3)
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pp. 91-96
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