scholarly journals Disodium 5-Cyanoisothiazoledithiolate as a Starting Material for Preparation of New Conductive Solids

1987 ◽  
Vol 42 (8) ◽  
pp. 1050-1051 ◽  
Author(s):  
G. C. Papavassiliou ◽  
G. A. Mousdis ◽  
V. Gionis ◽  
J. S. Zambounis ◽  
S. Y. Yiannopoulos
Keyword(s):  
Cation Radical ◽  
Starting Material ◽  
Derivatives Of

AbstractStarting from disodium 5-cyanoisothiazoledithiolate som e new substituted derivatives of the tetrathiafulvalene and some metal 1,2-dithiolenes with at least an isothiazolo-ring have been prepared. From these com pounds a number of conductive cation radical salts have been obtained.

Tricyanomethanides of cation-radical salts of derivatives of tetrathiafulvalene and tetrathiotetracene

1993 ◽  
Vol 29 (2) ◽  
pp. 238-238
Author(s):  
V. R. Kokars ◽  
V. �. Kampar ◽  
O. Ya. Neiland
Keyword(s):  
Cation Radical ◽  
Derivatives Of

SYNTHESIS OF 1,1,1-TRICHLORO-2,2-BIS-(p-CYANOPHENYL)-ETHANE

1952 ◽  
Vol 30 (3) ◽  
pp. 203-207 ◽  
Author(s):  
Yvon Perron ◽  
Roger Barré
Keyword(s):  
Condensation Product ◽  
Starting Material ◽  
Derivatives Of

The synthesis of 1,1,1-trichloro-2,2-bis-(p-cyanophenyl)-ethane was carried out with the condensation product of chloral and toluene as starting material. This product was converted, through the corresponding tetraacetate, to 1,1,1-trichloro-2,2-bis-(p-aldehydophenyl)-ethane which in turn reacted with hydroxylamine to give the dioxime. The subsequent dehydration of the latter gave rise to the desired dinitrile. The corresponding dichloro derivatives of the oxime and nitrile were also prepared.

scholarly journals Antimonial analogues of the acridine series. Dilhydrostibacridines

1933 ◽  
Vol 143 (848) ◽  
pp. 38-47 ◽  
Keyword(s):  
Nitro Derivative ◽  
Starting Material ◽  
Arsenic Compounds ◽  
Ring Systems ◽  
Nitrogen Ring ◽  
Derivatives Of

In pursuing our investigation out the antimony analogues of certain nitrogen ring-systems, we Lave now succeeded in obtaining derivatives of dilhydrostibacridines, of when some of the corresponding arsenic compounds have been studied recently by Gump and Stolzenburg. The starting material for the work was o -aminodiphenylmethane obtained from the corresponding nitro derivative when, in turn, was prepared from o -nitrobenzyl chloride and benzene by Taneseseu's modification of the Friedel-Crafts reaction.

New Derivatives of Lupeol and Their Biological Activity

Molbank ◽  
10.3390/m1306 ◽  
2021 ◽  
Vol 2021 (4) ◽  
pp. M1306
Author(s):  
Hoang-Thuy-Tien Le ◽  
Quoc-Cuong Chau ◽  
Thuc-Huy Duong ◽  
Quyen-Thien-Phuc Tran ◽  
Nguyen-Kim-Tuyen Pham ◽  
...  
Keyword(s):  
Biological Activity ◽  
Natural Product ◽  
Starting Material ◽  
Chemical Structures ◽  
Spectroscopic Analyses ◽  
Ic50 Value ◽  
Derivatives Of

The natural product lupeol (1) was isolated from Bombax ceiba leaves, which were used as starting material in the semisynthetic approach. Three new derivatives (2a, 2b, and 3) were synthesized using oxidation and aldolization. Their chemical structures were elucidated by spectroscopic analyses (HRESIMS and NMR). Compounds 3 showed significant α-glucosidase inhibition with an IC50 value of 202 µM, whereas 2a and 2b were inactive.

Dichalcogenane Derivatives of Methylenedithio(ethylenedithio)tetrathiafulvalene (MET) and a Derived Metallic Cation-Radical Salt with Screwed Donor Stacks

2001 ◽  
Vol 30 (1) ◽  
pp. 86-87 ◽  
Author(s):  
Jun-ichi Yamada ◽  
Takashi Mangetsu ◽  
Hiroki Akutsu ◽  
Shin’ichi Nakatsuji ◽  
Hiroyuki Nishikawa ◽  
...  
Keyword(s):  
Cation Radical ◽  
Metallic Cation ◽  
Radical Salt ◽  
Derivatives Of

scholarly journals Aerobic oxidation of cumene catalysed by 4-alkyloxycarbonyl-N-hydroxyphthalimide

2014 ◽  
Vol 12 (11) ◽  
pp. 1176-1182 ◽  
Author(s):  
Kornela Kasperczyk ◽  
Beata Orlińska ◽  
Jan Zawadiak
Keyword(s):  
Oxidation Reaction ◽  
Aerobic Oxidation ◽  
Starting Material ◽  
Trimellitic Anhydride ◽  
Cumene Oxidation ◽  
Derivatives Of

Abstract4-Hexyloxycarbonyl-, 4-dodecyloxycarbonyl- and 4-hexadecyloxycarbonyl-N-hydroxyphthalimides were synthesised using trimellitic anhydride chloride as the starting material. The obtained lipophilic derivatives of N-hydroxyphthalimide were applied as catalysts of the cumene oxidation reaction with oxygen performed in polar acetonitrile, in non-polar tert-butylbenzene and in the absence of a solvent. The courses of reactions catalysed by N-hydroxyphthalimide and its derivatives were compared.

1-(4-Cyclopentylphenyl)ethylamine and derivatives: Synthesis and pharmacological screening

1981 ◽  
Vol 46 (9) ◽  
pp. 2234-2244 ◽  
Author(s):  
Zdeněk Vejdělek ◽  
Jiří Holubek ◽  
Marie Bartošová ◽  
Miroslav Protiva
Keyword(s):  
Local Anaesthetic ◽  
Title Compound ◽  
Starting Material ◽  
Ritter Reaction ◽  
Hypotensive Activity ◽  
Substitution Reactions ◽  
Spasmolytic Activity ◽  
Pharmacological Screening ◽  
Neurotropic Effects ◽  
Derivatives Of

Reduction of 4-cyclopentylacetophenone oxime gave the title compound II which was transformed by a combination of acylation, alkylation, reduction and substitution reactions to compounds III-XI. 2-Benzylcyclopentanone oxime was reduced to 2-benzylcyclopentylamine (XVI) and converted by a reaction with methylmagnesium iodide and by the following Ritter reaction to the formamide derivative XVIII which was used as the starting material for preparing amines XIX-XXI. The local anaesthetic and spasmolytic activity were the most typical neurotropic effects of derivatives of compound II. 2-Benzyl-1-methylcyclopentylamine and derivatives XIX-XXI have some hypotensive activity.

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