cumene oxidation
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The cumene oxidation and cumene hydroperoxide decomposition in the presence of Zn, Cd or Hg 2-ethylhexanoate: Kinetic model and analysis of its sensitivity

2021 ◽  
Vol 515 ◽  
pp. 111886
Author(s):  
N.V. Ulitin ◽  
Kh.E. Kharlampidi ◽  
К.A. Tereshchenko ◽  
N.A. Novikov ◽  
D.A. Shiyan ◽  
...  
Keyword(s):  
Kinetic Model ◽  
Cumene Hydroperoxide ◽  
Cumene Oxidation ◽  
Hydroperoxide Decomposition

The influence of Fe(III) acetylacetonate and o-phenanthroline towards improvement of NHPI-catalyzed cumene oxidation

2021 ◽  
Vol 515 ◽  
pp. 111929
Author(s):  
N.I. Kuznetsova ◽  
I.E. Karmadonova ◽  
L.I. Kuznetsova ◽  
D.E. Babushkin
Keyword(s):  
Cumene Oxidation

scholarly journals Inhibitory effect of Zn 2+ on the chain‐initiation process of cumene oxidation

2021 ◽  
Author(s):  
Zhicheng Chen ◽  
Yuhang Li ◽  
Yonghai Cao ◽  
Qiao Zhang ◽  
Hao Yu ◽  
...  
Keyword(s):  
Inhibitory Effect ◽  
Chain Initiation ◽  
Cumene Oxidation ◽  
Initiation Process

Design of cumene oxidation process

2021 ◽  
Vol 161 ◽  
pp. 108314
Author(s):  
Kh.E. Kharlampidi ◽  
T.Sh. Nurmurodov ◽  
N.V. Ulitin ◽  
К.A. Tereshchenko ◽  
N.P. Miroshkin ◽  
...  
Keyword(s):  
Oxidation Process ◽  
Cumene Oxidation

The kinetic modeling of cumene oxidation taking into account oxygen mass transfer

2020 ◽  
Vol 392 ◽  
pp. 123811
Author(s):  
Kh.E. Kharlampidi ◽  
К.A. Tereshchenko ◽  
T.Sh. Nurmurodov ◽  
D.A. Shiyan ◽  
N.P. Miroshkin ◽  
...  
Keyword(s):  
Mass Transfer ◽  
Kinetic Modeling ◽  
Oxygen Mass Transfer ◽  
Cumene Oxidation

Trace amounts of Cu(OAc)2 boost the efficiency of cumene oxidation catalyzed by carbon nanotubes washed with HCl

2020 ◽  
Vol 10 (8) ◽  
pp. 2523-2530
Author(s):  
Jie Deng ◽  
Yuhang Li ◽  
Yonghai Cao ◽  
Hongjuan Wang ◽  
Hao Yu ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Cumene Oxidation

Trace amounts of Cu(OAc)2 significantly improve the activity and selectivity of cumene oxidation catalyzed by HCl-washed carbon nanotubes.

A kinetics study on cumene oxidation catalyzed by carbon nanotubes: Effect of N-doping

2018 ◽  
Vol 177 ◽  
pp. 391-398 ◽  
Author(s):  
Chunlin Mu ◽  
Yonghai Cao ◽  
Hongjuan Wang ◽  
Hao Yu ◽  
Feng Peng
Keyword(s):  
Carbon Nanotubes ◽  
Kinetics Study ◽  
Cumene Oxidation ◽  
N Doping

Kinetics and Mechanism of Cumene Oxidation Initiated by N -Hydroxyphthalimide

2017 ◽  
Vol 50 (1) ◽  
pp. 3-14 ◽  
Author(s):  
V. N. Sapunov ◽  
E. A. Kurganova ◽  
G. N. Koshel
Keyword(s):  
Kinetics And Mechanism ◽  
Cumene Oxidation

scholarly journals Isopropylbenzene oxidation reaction computer simulation

2017 ◽  
Author(s):  
Mikhail K. Vovdenko ◽  
◽  
Irek M. Gubaidulin ◽  
Kamila F. Koledina ◽  
Sergey N. Koledin ◽  
...  
Keyword(s):  
Computer Simulation ◽  
Kinetic Models ◽  
Oxidation Reaction ◽  
Intermediate Stage ◽  
Wide Spread ◽  
Cumene Oxidation ◽  
Chain Reactions ◽  
The World ◽  
Influence Degree

Isopropylbenzene (cumene) oxidation by air oxygen is intermediate stage of phenol and acetone production in cumene method. Cumene method of synthesis is currently the most wide-spread in the world to produce these two chemicals. Reaction is radical-chained and there also unwanted byproducts received along with desired ones. This reaction has been subject of study since 30th of XX century. Different authors propose different ways of chain reactions, initiation mechanisms and influence degree of different factors and parameters during process. In this paper different kinetic models of this reaction are compared and results of computations are shown.

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