Synthese und Kristallstruktur von [Na(15-Krone-5)]2S6 / Synthesis and Crystal Structure of [Na(15-crown-5)]2S6
1992 ◽
Vol 47
(8)
◽
pp. 1063-1066
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Keyword(s):
X Ray
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[Na(15-crown-5)]2S6 was obtained from Na2S4 und 15-crown-5 in acetonitrile. Its crystal structure was determined by X-ray diffraction with 2968 observed reflexions, R = 0.119. Crystal data: a = 861.4(9), b = 1006(1), c = 2097(1) pm, α = 89.7(1), β = 100.20(8), γ = 114.6(1)°, Ζ = 2, space group Ρ 1̄. The chain-like S62- ion has transoid conformations, each of its terminal atoms is in contact with one Na+ ion which in turn is coordinated with one crown ether molecule.
1987 ◽
Vol 42
(4)
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pp. 410-414
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Keyword(s):
1990 ◽
Vol 45
(10)
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pp. 1393-1397
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1992 ◽
Vol 47
(8)
◽
pp. 1075-1078
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Keyword(s):