Übergangsmetallkomplexe mit Schwefelliganden, XCII. Oxidation von Thiolat-Amin- zu Schiffbase-Eisen(II)-Komplexen. Röntgenstrukturanalyse und Reaktivität von [Fe('N2S2')]2 (′N2S2′2- = Glyoxal-bis(2-mercaptoanil)(2 – )) / Transition Metal Complexes with Sulfur Ligands, XCII. Oxidation of Thiolate Amine to Schiff Base Iron(II) Complexes. X-Ray Structure Analysis and Reactivity of [Fe(′N2S2')]2 (′N2S2′2- = Glyoxal-bis(2-mercaptoanil)(2–))
1992 ◽
Vol 47
(11)
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pp. 1545-1550
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Keyword(s):
Oxidation of [Fe(CO)2(′N2H2S2′')] (1) (′N2H2S2'2- = 1,2-ethanediamine-N,N′-bis(2-benzenethiolate)(2—)) gave insoluble [Fe(′N2S2')]2 (2) ('N2S2'2- = glyoxal-bis(2-mercaptoanil)(2—)). Dinuclear, thiolato-bridged 2 was characterized by single crystal X-ray structure analysis. It does not react with CO or H2, but yields bis or mono adducts with PR3 (R = Me, n-Bu, Cy).
1993 ◽
Vol 48
(7)
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pp. 875-885
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Keyword(s):
1991 ◽
Vol 46
(12)
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pp. 1601-1608
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2006 ◽
Vol 31
(5)
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pp. 580-585
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Keyword(s):
2018 ◽
Vol 1152
◽
pp. 223-231
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2015 ◽
Vol 2015
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pp. 1-14
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