The Crystal Structure of the Tetrameric Adduct of Antimony Trichloride and Phosphoryl Isothiocyanate, [SbCl3·OP(NCS)3]4
1994 ◽
Vol 49
(4)
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pp. 441-444
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Keyword(s):
X Ray
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The crystal and molecular structure of the tetrameric complex of the composition [SbCl3·OP(NCS)3]4 synthesized from SbCl3 and OP(NCS)3 in CCl4 waso determined by X-ray crystallography [143 m space group, cubic system with a = 13.927(4) Å]. The complex exhibits a tetranuclear "cage" structure with a [Sb4O4] core which consists of μ3-bridging oxygen and six coordinate antimony(III) atoms; the Sb-O distance, 3.060 Å, is exceptionally long.
1986 ◽
Vol 51
(11)
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pp. 2521-2527
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1998 ◽
Vol 53
(5-6)
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pp. 634-636
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1982 ◽
Vol 47
(10)
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pp. 2623-2632
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2000 ◽
Vol 55
(12)
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pp. 1124-1130
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2017 ◽
Vol 73
(11)
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pp. 937-940
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Keyword(s):
1978 ◽
Vol 56
(18)
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pp. 2491-2492
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2001 ◽
Vol 2001
(4)
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pp. 162-164
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