Synthesis and Crystal Structure of a Novel Polymeric Lead(II) Complex with Thiosemicarbazonato and Thiocyanate Ligands
2001 ◽
Vol 56
(6)
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pp. 517-520
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Keyword(s):
X Ray
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AbstractA novel heptacoordinated thiosemicarbazonato lead(II) complex [Pb(4ML)(SCN)] (4ML = 2-Acetylpyridine-4N-methylthiosemicarbazonato) was synthesized and characterized by conventional methods (IR and elemental analysis) and single-crystal X-ray diffraction. [Pb(4ML)(SCN)] shows an unusual polymeric structure in which the lead atom is hexa-coordinate, the deprotonated thiosemicarbazone both chelates and bridges, and the thiocyanate group acts as bridge between lead(II)-thiosemicarbazonate fragments. There is hydrogen-bonding between the polymeric chains. The complex crystallizes in the triclinic space group P 1̅̅ with a = 7.461(2), b = 9.572(2), c = 11.235(2) Å, α = 66.51(3), β = 84.01(3), γ = 68.75(3)°, V = 685.1(2) Å3, Z = 2.
2014 ◽
Vol 881-883
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pp. 205-210
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1994 ◽
Vol 49
(12)
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pp. 1654-1658
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1992 ◽
Vol 47
(4)
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pp. 460-464
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Keyword(s):
2010 ◽
Vol 65
(5)
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pp. 607-610
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2011 ◽
Vol 396-398
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pp. 959-962
2013 ◽
Vol 834-836
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pp. 515-518
2009 ◽
Vol 64
(1)
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pp. 141-144
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Keyword(s):