Synthesis and Crystal Structure of the Flexible Ligand Coordination Polymer [Co3(bpd)5.5(NCS)6(NH3)]n⋅2H2O(bpd= 1,4-bis (4-pyridyl)-2,3-diaza-1,3-butadiene)

2013 ◽  
Vol 803 ◽  
pp. 80-84
Author(s):  
Yu Qi Liu ◽  
Yong Yang ◽  
Rui Yang ◽  
Xiao Jun Xu
Keyword(s):  
Crystal Structure ◽  
Infrared Spectroscopy ◽  
Coordination Polymer ◽  
Single Crystal ◽  
X Ray Diffraction ◽  
Synthesis And Crystal Structure ◽  
X Ray ◽  
Elemental Analyses ◽  
Ligand Coordination ◽  
Point Symbol

A novel metalorganic coordination polymer, namely [Co3(bpd)5.5(NCS)6(NH3)]n2H2O (1) (bpd=1,4-bis (4-pyridyl)-2,3-diaza-1,3-butadiene), has been synthesized and characterized by elemental analyses, infrared spectroscopy, and single-crystal X-ray diffraction. Compound 1 presents 2D[3,4,-connected 3-nodal net with the point symbol (4268210)(4462)(8210). In addition, four identical 2D single nets is interlocked with each other in parallel, thus directly leading to the formation of a polycatenated layer (2D2D).

Synthesis and Crystal Structure of [(μ-Biphenyl-3,3'-Dicarboxylato)Manganese(II)]

2012 ◽  
Vol 531 ◽  
pp. 124-127
Author(s):  
Guang Yin Wang
Keyword(s):  
Crystal Structure ◽  
Coordination Polymer ◽  
Single Crystal ◽  
Elemental Analysis ◽  
Metal Center ◽  
X Ray Diffraction ◽  
Synthesis And Crystal Structure ◽  
X Ray ◽  
Hydrothermal Reactions

Hydrothermal reactions of biphenyl-3,3'-dicarboxylate acid (H2bpda) with Manganese(II) chloride gave rise to one new coordination polymer, namely, [Mn(bpda)]n. It was characterized by elemental analysis and single - crystal X - ray diffraction methods. This compound has one Mn metal center and shows a 3D uninterpenetrating framework

Synthesis and Crystal Structure of a New 1D Oxamidato-bridged Heterobimetallic Polymer

2010 ◽  
Vol 65 (5) ◽  
pp. 607-610 ◽  
Author(s):  
Wei Jiang Lou ◽  
Yun Zhang ◽  
Hong Cui ◽  
Bao Lin Liu ◽  
Ruo Jie Tao
Keyword(s):  
Crystal Structure ◽  
Coordination Polymer ◽  
Single Crystal ◽  
Terephthalic Acid ◽  
X Ray Diffraction ◽  
Triclinic Space Group ◽  
Synthesis And Crystal Structure ◽  
Space Group ◽  
X Ray

A new 1D ladder-like chain coordination polymer, namely, {[Cu(aeoe)Zn(H2O)3 ・ 1.5H2O]2}n (H4aeoe = 2-(2-(2-aminoethylamino)-2-oxoacetamido)terephthalic acid) has been synthesized and characterized by IR, thermogravimetric and single-crystal X-ray diffraction analyses (triclinic, space group P1̄, with a = 9.443(7), b = 9.519(7), c = 11.124(9) Å , α = 65.094(10)°, β = 77.559(10)°, γ = 81.752(10)°, Z = 1).

Synthesis, IR spectrum, thermal behaviour and crystal structure of a novel one-dimensional cyano-bridged zinc(II)/nickel(II) complex

2005 ◽  
Vol 220 (1) ◽  
Author(s):  
Ahmet Karadag ◽  
Hümeyra Pasaoglu ◽  
Gökhan Kastas ◽  
Orhan Büyükgüngör
Keyword(s):  
Crystal Structure ◽  
Thermal Analysis ◽  
Coordination Polymer ◽  
Single Crystal ◽  
Ir Spectrum ◽  
Polymeric Chain ◽  
X Ray Diffraction ◽  
Bimetallic Complex ◽  
One Dimensional ◽  
X Ray

AbstractThe cyano-bridged heteronuclear coordination polymer of zinc(II)/nickel(II) has been prepared by N-(2-hydroxyethyl)-ethylendiamine (hydet-en), alternatively named 2-(2-aminoethylamino)-ethanol and characterised by IR and thermal analysis. In the bimetallic complex, the decomposition of hydet-en ligands is seen to be endothermic whereas that of the cyano ligands is found to be exothermic. The crystal structure of the complex has been determined by single-crystal X-ray diffraction. The crystal structure of the zinc(II)-nickel(II) complex consists of a one-dimensional polymeric chain –Zn(hydet-en)

Two copper(II) coordination polymers constructed by bis(4-(1H-imidazol-1-yl)phenyl)methanone and dicarboxylate ligands

2017 ◽  
Vol 72 (4) ◽  
pp. 257-261 ◽  
Author(s):  
Gao-Feng Wang ◽  
Xiao Zhang ◽  
Shu-Wen Sun ◽  
Hong Sun ◽  
Hui Li ◽  
...  
Keyword(s):  
Infrared Spectroscopy ◽  
Single Crystal ◽  
Weak Interactions ◽  
X Ray Diffraction ◽  
X Ray ◽  
Elemental Analyses ◽  
Solvothermal Methods ◽  
Solid State Structures ◽  
Aromatic Carboxylate ◽  
Neutral Metal

AbstractTwo new copper(II) complexes, {[Cu(bipmo)(npa)]}n (1) and {[Cu(bipmo)(pa)]}n (2) (bipmo=bis(4-(1H-imidazol-1-yl)phenyl)methanone), were synthesized by solvothermal methods and structurally characterized by elemental analyses, infrared spectroscopy, and single-crystal X-ray diffraction. The results from single-crystal X-ray diffraction data indicate that the solid state structures of 1 and 2 consist of neutral metal aromatic carboxylate layers, which are pillared by the weak interactions to generate 3D architectures. The topological structures of 1 and 2 are uninodal nets based on 4-connected nodes with the Schläfli symbol of (65·8).

Synthesis, Structure and Properties of Two-Dimensional Coordination Polymer Based on 3,5-di(benzimidazol-1-yl)pyridine

2020 ◽  
Vol 42 (2) ◽  
pp. 249-249
Author(s):  
Guo Jun Wu Guo Jun Wu
Keyword(s):  
Infrared Spectroscopy ◽  
Coordination Polymer ◽  
Single Crystal ◽  
Photocatalytic Degradation ◽  
Elemental Analysis ◽  
Solvothermal Reaction ◽  
Two Dimensional ◽  
Structure And Properties ◽  
X Ray Diffraction ◽  
X Ray

[Cu(L)(AIP)·1.5H2O]n (1) [L= 3,5-di(benzimidazol-1-yl)pyridine, H2AIP= 5-aminoisophthalic acid] was prepared by the solvothermal reaction, which was characterized by single-crystal X–ray diffraction, infrared spectroscopy, and elemental analysis. 1 exhibits an infinite two dimensional [Cu(AIP)]n sheet parallel to (0 1 1) crystal plane. Furthermore, complex 1 displays good photocatalytic degradation of methyl blue (MB).

Synthesis and Crystal Structure of the Triple-decker Complex [(η5-C5Me5)- Ru(μ,η5-1,3-C3B2Me5)RhCl- (Ph2PCH2)2]

2009 ◽  
Vol 64 (1) ◽  
pp. 141-144 ◽  
Author(s):  
Yong Nie ◽  
Thomas Oeser ◽  
Walter Siebert
Keyword(s):  
Crystal Structure ◽  
Single Crystal ◽  
Diffraction Study ◽  
X Ray Diffraction ◽  
Synthesis And Crystal Structure ◽  
X Ray

The dimer [(η5-C5Me5)Ru(C3B2Me5)RhCl]2 (2) reacts with 1,2-bis(diphenylphosphino)ethane (dppe) to give the triple-decker complex [(η5-C5Me5)Ru(C3B2Me5)Rh- (dppe)Cl] (3). Its constitution follows from NMR and MS data, and a single-crystal X-ray diffraction study.

A Mn(II) coordination polymer from a polycarboxylate-containing ligand: synthesis, structural characterization, and properties

2017 ◽  
Vol 72 (12) ◽  
pp. 937-940 ◽  
Author(s):  
Xiao-Hong Zhu ◽  
Xiao-Chun Cheng ◽  
Yun-Hua Qian
Keyword(s):  
Magnetic Properties ◽  
Infrared Spectroscopy ◽  
Coordination Polymer ◽  
Single Crystal ◽  
Structural Characterization ◽  
X Ray Diffraction ◽  
Hydrothermal Conditions ◽  
Thermogravimetric Analyses ◽  
X Ray ◽  
3D Framework

AbstractThe neutral, four-fold protonated pyridine-3,5-dicarbox(3,5-dicarboxylatoanilide) (H4L) reacts with Mn(II) salts under hydrothermal conditions to yield a new complex: [Mn2(L)(H2O)2]·H2O (1), which has been characterized by single crystal X-ray diffraction, infrared spectroscopy, and elemental and thermogravimetric analyses. Complex 1 exhibits a binodal (4,8)-connected 3D framework with flu (412.612.84)(46)2 topology. The magnetic properties of 1 were investigated.

Synthesis and Crystal Structure of a Fe(II,III) Complex with 2-(4΄-Chlorine-benzoyl)-benzoic acid and 3-(2-Pyridyl)pyrazole

2013 ◽  
Vol 634-638 ◽  
pp. 2592-2595
Author(s):  
Qing Wei Wang ◽  
Ting Feng Lu ◽  
Jia Guo ◽  
Xiu Mei Li
Keyword(s):  
Crystal Structure ◽  
Benzoic Acid ◽  
Monoclinic Space Group ◽  
X Ray Diffraction ◽  
Organic Complex ◽  
Synthesis And Crystal Structure ◽  
X Ray ◽  
Elemental Analyses ◽  
Metal Organic Complex ◽  
Metal Organic

A new metal-organic complex FeII2FeIII2(cbba)4(L)6 (Hcbba = 2-(4΄-chlorine-benzoyl) benzoic acid, L = 3-(2-pyridyl)pyrazole) 1 has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction, elemental analyses, TG and IR spectroscopy. The compound crystallizes in monoclinic, space group Cc with a = 17.729(5), b = 15.919(5), c = 33.650(5) Å, β = 92.058(5)°, V = 9491(4) Å3, C104H68Cl4Fe4N18O12, Mr = 2126.96, Dc = 1.489 g/cm3, μ(MoKα) = 0.786 mm1, F(000) = 4344, Z = 4, the final R = 0.0559 and wR = 0.1122 for 12093 observed reflections (I > 2(I)).

Hydrothermal Synthesis and Crystal Structure of a Meso-Helical Chain Based on Lindqvist Polyoxometalates

2013 ◽  
Vol 68 (4) ◽  
pp. 345-350 ◽  
Author(s):  
Chun-Jing Zhang ◽  
Rui Fang ◽  
Yan Yu ◽  
Hai-Jun Pang ◽  
Hui-Yuan Ma ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Infrared Spectroscopy ◽  
Hydrothermal Synthesis ◽  
Chain Structure ◽  
Helical Chain ◽  
X Ray Diffraction ◽  
Hybrid Compound ◽  
Monoclinic System ◽  
Synthesis And Crystal Structure ◽  
X Ray

A new Lindqvist polyoxometalate-based hybrid compound with a helical chain structure, [Cu(bipy)2][W6O19] (1), (bipy = 2;20`-bipyridine), has been hydrothermally synthesized and characterized by elemental analysis, infrared spectroscopy, thermogravimetry, and single-crystal X-ray diffraction. The compound crystallizes in the space group C2/c of the monoclinic system. In 1, the [W6O19]2- anions are connected alternately with [Cu(bipy)2]2+ subunits to form a meso-helical chain. To our knowledge, this structure represents the first example of a helical chain structure consisting of the hexatungstate anion [W6O19]2-. The electrochemical properties of the title compound have been studied.

Synthese und Kristallstruktur von Triphenyltelluroniumsulfid / Synthesis and Crystal Structure of Triphenyltelluroniumsulfide

1994 ◽  
Vol 49 (12) ◽  
pp. 1654-1658 ◽  
Author(s):  
Markus Wieber ◽  
Stefan Lang ◽  
Stefan Rohse ◽  
Ralph Habersack ◽  
Christian Burschka
Keyword(s):  
Crystal Structure ◽  
Single Crystal ◽  
Title Compound ◽  
Spectroscopic Characterization ◽  
Unit Cell ◽  
X Ray Diffraction ◽  
Triclinic Space Group ◽  
Synthesis And Crystal Structure ◽  
X Ray ◽  
Cell Parameters

The synthesis of triphenyltelluroniumsulfide (Ph3TeS)4 is described together with a NMR-spectroscopic characterization. The structure of the title compound was determined by single crystal X-ray diffraction. Crystals of triphenyltelluroniumsulfide are triclinic (space group P1) with the cell parameters a = 1178.0(3) pm. b = 1295.8(6) pm. c = 1298.7(4) pm, α = 77.67(3)°, β = 82.18(2)°, γ = 66.00(2)° (V = 1766(1) × 106 pm3) and Z = 2. The compound appears to form a step-like structure of two [Ph3TeS]2 units and crystallizes with two molecules of CH2Cl2 per unit cell.

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