Helical chain Ag(I) complexes with a tridentate N-donor ligand: syntheses, structural characterization, and properties

2015 ◽  
Vol 70 (12) ◽  
pp. 851-856 ◽  
Author(s):  
Chun-Hua Dai ◽  
Fu-Lin Mao
Keyword(s):  
Ir Spectroscopy ◽  
Single Crystal ◽  
Structural Characterization ◽  
Fluorescence Properties ◽  
Helical Chain ◽  
Donor Ligand ◽  
Thermogravimetric Analyses ◽  
X Ray

AbstractThe tridentate N-donor ligand 2,6-di(2-oxazolyl)pyridine (L) reacts with AgClO4 and AgPF6 to yield two new complexes, {[Ag5(L)5](ClO4)5}n (1) and {[Ag5(L)5](PF6)5}n (2), which have been characterized by single-crystal and powder X-ray diffractions, IR spectroscopy, and elemental and thermogravimetric analyses. Complexes 1 and 2 are isotypic, displaying helical chain structures. The fluorescence properties of 1 and 2 were investigated.

A Cd complex with a di(imidazolyl)benzene ligand: synthesis, structural characterization, and fluorescence properties

2017 ◽  
Vol 72 (8) ◽  
pp. 585-588
Author(s):  
Fu-Lin Mao ◽  
Chun-Hua Dai
Keyword(s):  
Ir Spectroscopy ◽  
Single Crystal ◽  
Elemental Analysis ◽  
Structural Characterization ◽  
Structure Determination ◽  
Fluorescence Properties ◽  
X Ray Diffraction ◽  
Orthorhombic System ◽  
X Ray ◽  
2D Network

AbstractA new cadmium-organic network [Cd(L)(SO4)] (1) [L=1,3-di(4-imidazolyl)benzene] has been synthesized and characterized by single-crystal X-ray structure determination, IR spectroscopy, elemental analysis, and powder X-ray diffraction. The complex crystallizes in the orthorhombic system with space group Pnma and displays a binodal (3,5)-connected 2D network with (42.67.8)(42.6) topology. The fluorescence properties of complex 1 were investigated.

A Mn(II) coordination polymer from a polycarboxylate-containing ligand: synthesis, structural characterization, and properties

2017 ◽  
Vol 72 (12) ◽  
pp. 937-940 ◽  
Author(s):  
Xiao-Hong Zhu ◽  
Xiao-Chun Cheng ◽  
Yun-Hua Qian
Keyword(s):  
Magnetic Properties ◽  
Infrared Spectroscopy ◽  
Coordination Polymer ◽  
Single Crystal ◽  
Structural Characterization ◽  
X Ray Diffraction ◽  
Hydrothermal Conditions ◽  
Thermogravimetric Analyses ◽  
X Ray ◽  
3D Framework

AbstractThe neutral, four-fold protonated pyridine-3,5-dicarbox(3,5-dicarboxylatoanilide) (H4L) reacts with Mn(II) salts under hydrothermal conditions to yield a new complex: [Mn2(L)(H2O)2]·H2O (1), which has been characterized by single crystal X-ray diffraction, infrared spectroscopy, and elemental and thermogravimetric analyses. Complex 1 exhibits a binodal (4,8)-connected 3D framework with flu (412.612.84)(46)2 topology. The magnetic properties of 1 were investigated.

Syntheses, structures and magnetic properties of two CoII/NiII isostructural coordination polymers based on an asymmetric semirigid tricarboxylate ligand

2022 ◽  
Vol 78 (1) ◽  
Author(s):  
Shao-Dong Li ◽  
Feng Su ◽  
Cheng-Yong Zhou ◽  
Qi-Long Hu ◽  
Ya-Qi Li ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Ir Spectroscopy ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Magnetic Studies ◽  
Thermogravimetric Analyses ◽  
X Ray ◽  
Elemental Analyses

Two new isostructural complexes, namely, poly[aqua[μ3-2-(4-carboxyphenoxy)terephthalato-κ3 O 1:O 4:O 4′](1,10-phenanthroline-κ2 N,N′)cobalt(II)], [Co(C15H8O7)(C12H8N2)(H2O)] n or [Co(μ3-Hcpota)(phen)(H2O)] n , I, and poly[aqua[μ3-2-(4-carboxyphenoxy)terephthalato-κ3 O 1:O 4:O 4′](1,10-phenanthroline-κ2 N,N′)nickel(II)], [Ni(C15H8O7)(C12H8N2)(H2O)] n or [Ni(μ3-Hcpota)(phen)(H2O)] n , II, have been synthesized by solvothermal reactions. Complexes I and II were fully characterized by IR spectroscopy, elemental analyses, thermogravimetric analyses, and powder and single-crystal X-ray diffraction. They both present two-dimensional structures based on [M 2(μ-COO)2]2+ (M = CoII or NiII) dinuclear metal units with a fes topology and a vertex symbol (4·82). Interestingly, the positions of the two dimeric metal motifs and the two partially deprotonated Hcpota2− ligands reproduce regular flying butterfly arrangements flipped upside down and sharing wings in the ab plane. Magnetic studies indicate antiferromagnetic interactions (J = −5.21 cm−1 for I and −11.53 cm−1 for II) in the dimeric units, with Co...Co and Ni...Ni distances of 4.397 (1) and 4.358 (1) Å, respectively, that are related to double syn–anti carboxylate bridges.

Synthesis, structural characterization, and properties of three Ag(I) complexes with oxazoline-containing chiral ligands

2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Hai-Wei Kuai ◽  
Xiao-Chun Cheng ◽  
Xiao-Hong Zhu
Keyword(s):  
Optical Properties ◽  
Ir Spectroscopy ◽  
Single Crystal ◽  
Structural Characterization ◽  
Nonlinear Optical ◽  
Organic Ligands ◽  
Silver Complexes ◽  
X Ray Diffraction ◽  
X Ray ◽  
Silver Salts

Abstract The two enantiopure chiral organic ligands 2-[(S)-4-isopropyl-2-oxazolyl]quinoline (L1) and 2-[(S)-4-benzyl-2-oxazolyl]quinoline (L2) react with different silver salts to give rise to three new silver complexes [Ag(L1)2](SbF6) (1), [Ag(L1)(CH3CN)](ClO4) (2), and [Ag(L2)(NO3)] (3), which have been characterized by single-crystal X-ray diffraction, IR spectroscopy, elemental and thermogravimetric analyses. Complexes 1–3 all display discrete mononuclear structures. The nonlinear optical properties of 1–3 were investigated.

A Zn(II) complex from an imidazolyl-thiophene ligand: synthesis, structural characterization, and fluorescence

2018 ◽  
Vol 73 (6) ◽  
pp. 407-411
Author(s):  
Hai-Wei Kuai ◽  
Tao Hu ◽  
Ding-Yun Jiang ◽  
Xiao-Hong Zhu
Keyword(s):  
Ir Spectroscopy ◽  
Single Crystal ◽  
Single Crystals ◽  
Network Structure ◽  
Structural Characterization ◽  
Hydrothermal Reaction ◽  
X Ray Diffraction ◽  
Monoclinic System ◽  
Space Group ◽  
X Ray

AbstractThe hydrothermal reaction of ZnSO4 with 2,5-di(1H-imidazol-4-yl)thiophene (L) at 100°C yields a new complex [Zn(L)(SO4)]n (1). Complex 1 has been characterized by single-crystal X-ray diffraction, IR spectroscopy, and elemental and thermogravimetric analyses. It crystallizes in the monoclinic system, space group P21/c with Z=4, and shows a (44.62) network structure. Complex 1 shows fluorescence. Single crystals of L·2H2O were accidentally obtained in hydrothermal reaction attempts of L with MnCl2 at 120°C.

Syntheses, Spectral, Thermal And Structural Characterization Of 2-Hydroxyanilinium And 2-Amino-3-Hydroxy-Pyridinium Squarates

2007 ◽  
Vol 62 (6) ◽  
pp. 823-828
Author(s):  
Okan Zafer ◽  
Hümeyra Paşaoğlub ◽  
O. Ozan Yılan ◽  
Orhan Büyükgüngör
Keyword(s):  
Ir Spectroscopy ◽  
Single Crystal ◽  
Structural Characterization ◽  
Thermal Analyses ◽  
Squaric Acid ◽  
X Ray Diffraction ◽  
Monoclinic System ◽  
X Ray ◽  
Elemental Analyses

New salts of 2-hydroxyaniline and 2-amino-3-hydroxypyridine with squaric acid were synthesized and characterized by elemental analyses, IR spectroscopy and thermal analyses (TG, DTG and DTA). The crystal structures of bis(2-hydroxyanilinium) squarate, [(C6H8NO+)2(C4O4)2−] (1) and bis(2- amino-3-hydroxy-pyridinium) squarate dihydrate, [(C5H7N2O+)2(C4O4)2−] · 2 H2O (2) were determined by single crystal X-ray diffraction. Both compounds crystallize in the monoclinic system, space group P21/c. The organic ammonium squarates decompose in two thermal steps

A Co(II) complex based on a mixed N- and O-donor: synthesis, structural characterization, and properties

2017 ◽  
Vol 72 (3) ◽  
pp. 183-187 ◽  
Author(s):  
Xiao-Hong Zhu ◽  
Jing-Jing Xia ◽  
Hai-Yun Sang ◽  
Jing Chen
Keyword(s):  
Magnetic Properties ◽  
Single Crystal ◽  
Structural Characterization ◽  
Hydrothermal Reaction ◽  
X Ray Diffraction ◽  
Thermogravimetric Analyses ◽  
X Ray

AbstractThe hydrothermal reaction of 5,5′-[(pyridine-3,5-dicarbonyl)bis(azanediyl)]diisophthalic acid (H4L) with a Co(II) salt yields the new complex: [Co3(HL)2(H2O)4] (1), which has been characterized by single crystal X-ray diffraction, IR, and elemental and thermogravimetric analyses. Complex1exhibits a binodal (4,8)-connected 2D net structure with (420.68)(46)2topology. The magnetic properties of1were also investigated.

N-Heterocyclic Carbene Adducts of Cyclopalladated Ferrocenylpyridazine: Synthesis, Structural Characterization, and Application in ?-Arylation of Ketones with Aryl Chlorides

2012 ◽  
Vol 65 (4) ◽  
pp. 366 ◽  
Author(s):  
Chen Xu ◽  
Hong-Mei Li ◽  
Zhi-Qiang Wang ◽  
Wei-Jun Fu ◽  
Yu-Qing Zhang ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Ir Spectroscopy ◽  
Single Crystal ◽  
1H Nmr ◽  
Elemental Analysis ◽  
Structural Characterization ◽  
High Catalytic Activity ◽  
X Ray ◽  
Aryl Chlorides ◽  
Esi Ms

A new ferrocene-based ligand 3-chloro-6-pyridazinylferrocene 1 and its N-heterocyclic carbene adducts 2–3 were synthesized and characterized by 1H NMR and IR spectroscopy, ESI-MS, and elemental analysis. Additionally, detailed structures of complexes 2–3 have been determined by single-crystal X-ray analysis. Complex 3 exhibited high catalytic activity for α-arylation of ketones with aryl chlorides. Typically, using 1 mol % catalyst in the presence of 1.5 equivalents of tBuOK as base in dioxane at 100°C provided coupled products in good yields.

A Mn(II) complex with an amide-containing ligand: synthesis, structural characterization, and magnetic properties

2019 ◽  
Vol 74 (5) ◽  
pp. 409-414
Author(s):  
Xiao-Hong Zhu ◽  
Ding-Yun Jiang ◽  
Xiao-Chun Cheng ◽  
Deng-Hao Li ◽  
Wei-Gang Du
Keyword(s):  
Magnetic Properties ◽  
Single Crystal ◽  
Structural Characterization ◽  
Hydrothermal Reaction ◽  
Framework Structure ◽  
X Ray Diffraction ◽  
Thermogravimetric Analyses ◽  
X Ray ◽  
Ligand Synthesis

AbstractA new Mn(II) complex [Mn2(L)(H2O)3] · (H2O)4.8(1) was synthesizedviathe hydrothermal reaction of MnCl2 · 4H2O withN4,N4′-di(5-isophthalyl)biphenyl-4,4′-dicarboxamide (H4L). Complex1is characterized by single-crystal and powder X-ray diffraction, infrared spectroscopy, and elemental and thermogravimetric analyses.1exhibits a uninodal 5-connected 3Dbnnframework structure with (46.64) topology. The magnetic properties of1were investigated.

Syntheses and structural characterization of coordination polymers of Cu(II) and Zn(II) chlorobenzoates and bis(pyridin-4-yl)-substituted species

2015 ◽  
Vol 70 (2) ◽  
pp. 95-100 ◽  
Author(s):  
Fu-Lin Mao ◽  
Jian-Qing Tao ◽  
Chun-Hua Dai
Keyword(s):  
Ir Spectroscopy ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Network Structure ◽  
Structural Characterization ◽  
Chain Structure ◽  
X Ray Diffraction ◽  
X Ray ◽  
A Chain

AbstractThe reaction of Cu(II) nitrate with sodium 2-chlorobenzoate (NaL1) and (E)-1,2-di(pyridin-4-yl)ethene (dpe) yields a new complex [Cu(L1)2(dpe)(H2O)] (1). When Zn(II) nitrate reacts with sodium 4-chlorobenzoate (NaL2) and 1,2-di(pyridin-4-yl)ethane (dpa), [Zn(L2)2(dpa)]·CH3OH (2) is obtained. Complexes 1 and 2 have been characterized by single-crystal X-ray diffraction, IR spectroscopy, and elemental and thermogravimetric analyses. 1 shows a 3D CdS network structure with uninodal 4-connected (65.8) topology; complex 2 displays a chain structure.

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