Synthesis and structural characterization of two coordination polymers constructed by bis(4-(1H-imidazol-1-yl)phenyl)methanone and 5-(tert-butyl)isophthalate ligands
2019 ◽
Vol 74
(3)
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pp. 261-265
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Keyword(s):
X Ray
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AbstractTwo coordination polymers, {[Co(bipmo)(tbip)]·3H2O}n (1) and {[Cd(bipmo)(tbip)]·3H2O}n (2) (bipmo=bis(4-(1H-imidazol-1-yl)phenyl)methanone, H2tbip=5-tert-butylisophthalic acid), were synthesized by solvothermal methods and structurally characterized by elemental analyses, infrared spectroscopy, and single-crystal X-ray diffraction. The results from single-crystal X-ray diffraction data indicate that the solid state structures of 1 and 2 consist of metal-aromatic carboxylate layers, which are pillared by weak interactions to generate a three-dimensional network. The topological structures of 1 and 2 are uninodal nets based on 3-connected nodes with the Schläfli symbol of {63}.
2017 ◽
Vol 72
(4)
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pp. 257-261
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2014 ◽
Vol 70
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pp. 375-378
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2016 ◽
Vol 71
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2020 ◽
Vol 76
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pp. 236-243
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Vol 70
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pp. 165-169
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2022 ◽
Vol 78
(1)
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Vol 41
(6)
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pp. 365-369
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